42 Структура и динамика молекулярных систем, 2007 г., Выпуск №1 ɍȾɄ 539.128 ȽȿɆɂɇȺɅɖɇɕȿ ɉɈȼȿɊɏɇɈɋɌɇɈ-ȺɄɌɂȼɇɕȿ ȼȿɓȿɋɌȼȺ: ȾɂɇȺɆɂɑȿɋɄȺə ɋɌɊɍɄɌɍɊȺ ɇȺȾɆɈɅȿɄɍɅəɊɇɕɏ ȺȽɊȿȽȺɌɈȼ. ɆȿɌɈȾ ɗɉɊ ɋɉɂɇɈȼɕɏ ɁɈɇȾɈȼ1 ȼɵɥɟɝɠɚɧɢɧɚ ɇ.ɇ., Ɇɢɪɝɨɪɨɞɫɤɚɹ Ⱥ.Ȼ.*, Ɂɭɟɜ ɘ.Ɏ., ɉɚɧɤɪɚɬɨɜ ȼ.Ⱥ.** Ʉɚɡɚɧɫɤɢɣ ɢɧɫɬɢɬɭɬ ɛɢɨɯɢɦɢɢ ɢ ɛɢɨɮɢɡɢɤɢ Ʉɚɡɇɐ ɊȺɇ *ɂɧɫɬɢɬɭɬ ɨɪɝɚɧɢɱɟɫɤɨɣ ɢ ɮɢɡɢɱɟɫɤɨɣ ɯɢɦɢɢ ɢɦ. Ⱥ.ȿ.Ⱥɪɛɭɡɨɜɚ Ʉɚɡɇɐ ɊȺɇ Ɇɨɫɤɨɜɫɤɢɣ ɝɨɫɭɞɚɪɫɬɜɟɧɧɵɣ ɭɧɢɜɟɪɫɢɬɟɬ ɩɪɢɤɥɚɞɧɨɣ ɛɢɨɬɟɯɧɨɥɨɝɢɢ Ɇɨɥɟɤɭɥɵ ɝɟɦɢɧɚɥɶɧɵɯ ɉȺȼ, ɤɨɬɨɪɵɟ ɚɤɬɢɜɧɨ ɢɫɫɥɟɞɭɸɬɫɹ ɜ ɩɨɫɥɟɞɧɢɟ ɝɨɞɵ, ɫɨɞɟɪɠɚɬ ɞɜɟ ɝɢɞɪɨɮɨɛɧɵɟ ɰɟɩɢ ɢ ɞɜɟ ɝɢɞɪɨɮɢɥɶɧɵɟ ɝɨɥɨɜɧɵɟ ɝɪɭɩɩɵ, ɤɨɜɚɥɟɧɬɧɨ ɫɜɹɡɚɧɧɵɟ ɫɩɟɣɫɟɪɧɵɦ ɦɨɫɬɢɤɨɦ. Ɍɚɤɢɟ ɉȺȼ ɨɛɥɚɞɚɸɬ ɨɱɟɧɶ ɧɢɡɤɢɦɢ ɤɪɢɬɢɱɟɫɤɢɦɢ ɤɨɧɰɟɧɬɪɚɰɢɹɦɢ ɦɢɰɟɥɥɨɨɛɪɚɡɨɜɚɧɢɹ (ɄɄɆ) ɢ ɷɮɮɟɤɬɢɜɧɨ ɫɧɢɠɚɸɬ ɩɨɜɟɪɯɧɨɫɬɧɨɟ ɧɚɬɹɠɟɧɢɟ ɧɚ ɝɪɚɧɢɰɟ ɪɚɡɞɟɥɚ ɮɚɡ, ɪɟɡɤɨ ɨɬɥɢɱɚɹɫɶ ɜ ɷɬɢɯ ɫɜɨɣɫɬɜɚɯ ɨɬ ɨɞɧɨɰɟɩɨɱɟɱɧɵɯ ɉȺȼ. ȼ ɞɚɧɧɨɣ ɪɚɛɨɬɟ ɦɟɬɨɞɨɦ ɗɉɊ ɫɩɢɧɨɜɵɯ ɡɨɧɞɨɜ ɢɡɭɱɟɧɚ ɞɢɧɚɦɢɱɟɫɤɚɹ ɫɬɪɭɤɬɭɪɚ ɩɪɹɦɵɯ ɦɢɰɟɥɥ, ɨɛɪɚɡɨɜɚɧɧɵɯ ɚɥɤɢɥɚɦɦɨɧɢɣɧɵɦɢ ɝɟɦɢɧɚɥɶɧɵɦɢ ɉȺȼ (Ƚɟɦ-1-7) ɫ ɪɚɡɥɢɱɧɵɦɢ ɝɨɥɨɜɧɵɦɢ ɝɪɭɩɩɚɦɢ ɢ ɫɩɟɣɫɟɪɧɵɦɢ ɦɨɫɬɢɤɚɦɢ. + + Ƚɟɦ-1 [C12H25 (CH3)2 N (CH2)6 N (CH3)2 C12H25] Br 2 + + [C12H25 (C2H5)2 N (CH2)n N (C2H5)2 (C12H25)] Br 2 n = 4, 6,8 Ƚɟɦ-2-4 C12H25 + N (CH2)n + N C12H25 2 Br _ n = 4, 6 Ƚɟɦ-5, 6 + H + C12H25 (CH3)2 N (CH2)3 N (CH2)3 N(CH3)2 C12H25] Br 2 Ƚɟɦ-7 ɉɨɥɭɱɟɧɧɵɟ ɪɟɡɭɥɶɬɚɬɵ ɨɛɫɭɠɞɟɧɵ ɜ ɫɨɩɨɫɬɚɜɥɟɧɢɢ ɫ ɩɨɜɟɞɟɧɢɟɦ ɩɨɯɨɠɟɝɨ ɤɚɬɢɨɧɧɨɝɨ ɉȺȼ ɞɨɞɟɰɢɥɩɢɪɢɞɢɧɢɣ ɛɪɨɦɢɞɚ (ȾɞɉȻ), ɫɨɞɟɪɠɚɳɟɝɨ ɨɞɧɭ ɝɢɞɪɨɮɨɛɧɭɸ ɰɟɩɶ. 1 Ɋɚɛɨɬɚ ɜɵɩɨɥɧɟɧɚ ɩɪɢ ɩɨɞɞɟɪɠɤɟ Ɋɨɫɫɢɣɫɤɨɝɨ ɮɨɧɞɚ ɮɭɧɞɚɦɟɧɬɚɥɶɧɵɯ ɢɫɫɥɟɞɨɜɚɧɢɣ (ɝɪɚɧɬ ʋ 05-03-33110). Раздел 1 43 ɗɤɫɩɟɪɢɦɟɧɬɚɥɶɧɚɹ ɱɚɫɬɶ. Ⱦɥɹ ɩɪɢɝɨɬɨɜɥɟɧɢɹ ɪɚɫɬɜɨɪɨɜ ɛɵɥɢ ɢɫɩɨɥɶɡɨɜɚɧɵ ɥɚɛɨɪɚɬɨɪɧɵɟ ɨɛɪɚɡɰɵ Ƚɟɦ-1-7, ɩɨɥɭɱɟɧɧɵɟ ɤɜɚɬɟɪɧɢɡɚɰɢɟɣ ɫɨɨɬɜɟɬɫɬɜɭɸɳɢɯ ɞɢɚɦɢɧɨɜ ɞɨɞɟɰɢɥɛɪɨɦɢɞɨɦ, ɢ ȾɞɉȻ (Sigma), ɫɨɞɟɪɠɚɳɢɣ ɨɤɨɥɨ 99% ɨɫɧɨɜɧɨɝɨ ɜɟɳɟɫɬɜɚ. ȼ ɤɚɱɟɫɬɜɟ ɜɨɞɧɨɣ ɮɚɡɵ ɢɫɩɨɥɶɡɨɜɚɧ ɛɭɮɟɪɧɵɣ ɪɚɫɬɜɨɪ ɧɚ ɨɫɧɨɜɟ ɬɟɬɪɚɛɨɪɚɬɚ ɧɚɬɪɢɹ, ɪɇ10.0. ɋɩɟɤɬɪɵ ɗɉɊ ɪɚɫɬɜɨɪɨɜ ɩɪɢ ɤɨɧɰɟɧɬɪɚɰɢɢ ɉȺȼ 0.01Ɇ ɢ ɬɟɦɩɟɪɚɬɭɪɟ 250ɋ ɪɟɝɢɫɬɪɢɪɨɜɚɥɢ ɧɚ ɪɚɞɢɨɫɩɟɤɬɪɨɦɟɬɪɟ Ɋɗ1306 (USSR). ɋɩɢɧɨɜɵɦɢ ɡɨɧɞɚɦɢ ɫɥɭɠɢɥɢ ɦɨɥɟɤɭɥɵ 5-ɞɨɤɫɢɥ ɫɬɟɚɪɢɧɨɜɨɣ ɤɢɫɥɨɬɵ (5-ȾɋɄ), ɨɛɥɚɞɚɸɳɢɟ ɚɦɮɢɮɢɥɶɧɵɦɢ ɫɜɨɣɫɬɜɚɦɢ. ɗɬɨ ɩɨɡɜɨɥɹɟɬ ɢɦ ɜɫɬɪɚɢɜɚɬɶɫɹ ɜ ɦɟɠɮɚɡɧɵɣ ɫɥɨɣ ɦɢɰɟɥɥ, ɩɪɢɱɟɦ ɩɚɪɚɦɚɝɧɢɬɧɵɣ ɮɪɚɝɦɟɧɬ ɪɚɫɩɨɥɚɝɚɟɬɫɹ ɛɥɢɠɟ ɤ ɩɨɥɹɪɧɨɦɭ ɤɨɧɰɭ ɦɨɥɟɤɭɥɵ. Ɇɟɬɨɞɢɤɚ ɜɜɟɞɟɧɢɹ ɫɩɢɧɨɜɵɯ ɡɨɧɞɨɜ ɜ ɦɢɰɟɥɥɹɪɧɵɟ ɪɚɫɬɜɨɪɵ, ɭɫɥɨɜɢɹ ɪɟɝɢɫɬɪɚɰɢɢ ɢ ɫɩɨɫɨɛɵ ɦɚɬɟɦɚɬɢɱɟɫɤɨɣ ɨɛɪɚɛɨɬɤɢ ɫɩɟɤɬɪɨɜ ɗɉɊ ɨɩɢɫɚɧɵ ɜ [1]. Ɋɟɡɭɥɶɬɚɬɵ ɷɤɫɩɟɪɢɦɟɧɬɚ ɢ ɢɯ ɨɛɫɭɠɞɟɧɢɹ. Ɍɢɩ ɧɚɞɦɨɥɟɤɭɥɹɪɧɵɯ ɚɝɪɟɝɚɬɨɜ, ɨɛɪɚɡɨɜɚɧɧɵɯ ɝɟɦɢɧɚɥɶɧɵɦɢ ɉȺȼ, ɡɚɜɢɫɢɬ ɨɬ ɫɬɪɭɤɬɭɪɵ ɫɩɟɣɫɟɪɧɨɣ ɢ ɝɨɥɨɜɧɵɯ ɝɪɭɩɩ, ɞɥɢɧɵ ɝɢɞɪɨɮɨɛɧɵɯ ɰɟɩɟɣ. Ⱦɥɹ ɝɟɦɢɧɚɥɶɧɵɯ ɉȺȼ ɫ ɲɟɫɬɶɸ ɦɟɬɢɥɟɧɨɜɵɦɢ ɡɜɟɧɶɹɦɢ ɦɟɠɞɭ ɝɨɥɨɜɧɵɦɢ ɝɪɭɩɩɚɦɢ ɜ ɜɨɞɧɵɯ ɪɚɫɬɜɨɪɚɯ ɯɚɪɚɤɬɟɪɧɨ ɨɛɪɚɡɨɜɚɧɢɟ ɩɪɹɦɵɯ ɦɢɰɟɥɥ. Ɏɨɪɦɚ ɦɢɰɟɥɥ ɩɨ ɦɟɪɟ ɭɜɟɥɢɱɟɧɢɹ ɤɨɧɰɟɧɬɪɚɰɢɢ ɉȺȼ ɦɨɠɟɬ ɦɟɧɹɬɶɫɹ ɨɬ ɫɮɟɪɢɱɟɫɤɨɣ ɤ ɷɥɥɢɩɫɨɢɞɚɥɶɧɨɣ ɢ ɞɚɥɟɟ ɤ ɰɢɥɢɧɞɪɢɱɟɫɤɨɣ [2]. ȼɢɞ ɫɩɟɤɬɪɨɜ ɗɉɊ ɫɩɢɧɨɜɵɯ ɡɨɧɞɨɜ 5ȾɋɄ ɜ ɜɨɞɧɵɯ ɪɚɫɬɜɨɪɚɯ Ƚɟɦ-1-7 ɢ ȾȾɉȻ ɭɤɚɡɵɜɚɟɬ ɧɚ ɡɚɦɟɬɧɵɟ ɪɚɡɥɢɱɢɹ ɜ ɩɨɞɜɢɠɧɨɫɬɢ ɩɚɪɚɦɚɝɧɢɬɧɵɯ ɮɪɚɝɦɟɧɬɨɜ, ɧɚɯɨɞɹɳɢɯɫɹ ɜɧɭɬɪɢ ɦɟɠɮɚɡɧɨɝɨ ɫɥɨɹ ɦɢɰɟɥɥ ɪɚɡɧɵɯ ɨɛɪɚɡɰɨɜ. ɋɩɟɤɬɪɵ ɗɉɊ, ɧɚɛɥɸɞɚɟɦɵɟ ɞɥɹ Ƚɟɦ-1, 3, 4, 6 ɢ ȾɞɉȻ, ɫɨɫɬɨɹɬ ɢɡ ɬɪɟɯ ɥɢɧɢɣ ɫɜɟɪɯɬɨɧɤɨɣ (ɋɌ) ɫɬɪɭɤɬɭɪɵ ɪɚɡɥɢɱɧɨɣ ɢɧɬɟɧɫɢɜɧɨɫɬɢ, ɫɜɢɞɟɬɟɥɶɫɬɜɭɸɳɢɯ ɨ ɛɵɫɬɪɨɦ ɜɪɚɳɟɧɢɢ !N x O ɝɪɭɩɩɵ ɡɨɧɞɚ (WZA>>1, ɝɞɟ W - ɜɪɟɦɹ ɤɨɪɪɟɥɹɰɢɢ ɷɬɨɝɨ ɜɪɚɳɟɧɢɹ, ZȺ ɱɚɫɬɨɬɚ ɚɧɢɡɨɬɪɨɩɢɢ ɋɌ ɜɡɚɢɦɨɞɟɣɫɬɜɢɹ ɫɩɢɧɚ ɧɟɫɩɚɪɟɧɧɨɝɨ ɷɥɟɤɬɪɨɧɚ ɫ ɦɚɝɧɢɬɧɵɦ ɦɨɦɟɧɬɨɦ ɹɞɪɚ ɚɬɨɦɚ ɚɡɨɬɚ). ȼ ɷɬɨɦ ɫɥɭɱɚɟ ɞɥɹ ɯɚɪɚɤɬɟɪɢɫɬɢɤɢ ɞɢɧɚɦɢɱɟɫɤɨɣ ɫɬɪɭɤɬɭɪɵ ɦɟɠɮɚɡɧɨɝɨ ɫɥɨɹ ɦɢɰɟɥɥ ɢɫɩɨɥɶɡɭɸɬ ɜɪɟɦɹ ɤɨɪɪɟɥɹɰɢɢ W, ɩɨɫɤɨɥɶɤɭ ɨɧɨ ɨɩɪɟɞɟɥɹɟɬɫɹ ɦɢɤɪɨɨɤɪɭɠɟɧɢɟɦ ɩɚɪɚɦɚɝɧɢɬɧɨɝɨ ɮɪɚɝɦɟɧɬɚ ɡɨɧɞɚ. ɋɩɟɤɬɪɵ ɗɉɊ, ɧɚɛɥɸɞɚɟɦɵɟ ɞɥɹ ɪɚɫɬɜɨɪɨɜ Ƚɟɦ-2, 5, 7 ɫɨɞɟɪɠɚɬ, ɜ ɞɨɩɨɥɧɟɧɢɟ ɤ ɬɪɟɦ ɥɢɧɢɹɦ ɋɌ ɫɬɪɭɤɬɭɪɵ, ɜɧɟɲɧɢɟ ɲɢɪɨɤɢɟ ɩɢɤɢ (ȼɒɉ). ɗɬɨ ɫɜɢɞɟɬɟɥɶɫɬɜɭɟɬ ɨ ɡɚɦɟɬɧɨɦ ɡɚɦɟɞɥɟɧɢɢ ɜɪɚɳɟɧɢɹ ɩɚɪɚɦɚɝɧɢɬɧɨɝɨ ɮɪɚɝɦɟɧɬɚ ɡɨɧɞɚ (W > 3·10-9 ɧɫ). ȼ ɷɬɨɦ ɫɥɭɱɚɟ ɞɥɹ ɯɚɪɚɤɬɟɪɢɫɬɢɤɢ ɜɪɚɳɟɧɢɹ ɢɫɩɨɥɶɡɭɟɬɫɹ ɜɟɥɢɱɢɧɚ ɦɚɤɫɢɦɚɥɶɧɨɝɨ ɋɌ ɪɚɫɳɟɩɥɟɧɢɹ ɫɩɟɤɬɪɚ ɗɉɊ, 2Amax, ɤɨɬɨɪɚɹ ɱɭɜɫɬɜɢɬɟɥɶɧɚ ɤ ɚɦɩɥɢɬɭɞɟ ɢ ɫɤɨɪɨɫɬɢ 44 Структура и динамика молекулярных систем, 2007 г., Выпуск №1 ɞɜɢɠɟɧɢɹ ɧɢɬɪɨɤɫɢɥɶɧɨɝɨ ɮɪɚɝɦɟɧɬɚ. ɉɪɢ ɷɬɨɦ, ɱɟɦ ɛɨɥɶɲɟ ɜɟɥɢɱɢɧɚ 2Amax, ɬɟɦ ɛɨɥɟɟ ɡɚɬɪɭɞɧɟɧɨ ɜɪɚɳɟɧɢɟ ɝɪɭɩɩɵ !N x O, ɱɬɨ ɨɛɵɱɧɨ ɫɜɹɡɵɜɚɸɬ ɫ ɛɨɥɶɲɟɣ ɩɥɨɬɧɨɫɬɶɸ ɭɩɚɤɨɜɤɢ ɦɨɥɟɤɭɥ ɉȺȼ ɜɨɤɪɭɝ ɷɬɨɣ ɝɪɭɩɩɵ. ɉɚɪɚɦɟɬɪɵ, ɩɨɥɭɱɟɧɧɵɟ ɢɡ ɫɩɟɤɬɪɨɜ ɗɉɊ ɢ ɯɚɪɚɤɬɟɪɢɡɭɸɳɢɟ ɞɢɧɚɦɢɱɟɫɤɭɸ ɫɬɪɭɤɬɭɪɭ ɦɢɰɟɥɥ, ɨɛɪɚɡɭɸɳɢɯɫɹ ɜ ɜɨɞɧɵɯ ɪɚɫɬɜɨɪɚɯ Ƚɟɦ-1-7 ɢ ȾɞɉȻ, ɩɪɢɜɟɞɟɧɵ ɜ Ɍɚɛɥ. 1. Ɍɚɛɥɢɰɚ 1. ɉɚɪɚɦɟɬɪɵ, ɩɨɥɭɱɟɧɧɵɟ ɢɡ ɫɩɟɤɬɪɨɜ ɗɉɊ, ɯɚɪɚɤɬɟɪɢɡɭɸɳɢɟ ɞɢɧɚɦɢɱɟɫɤɭɸ ɫɬɪɭɤɬɭɪɭ ɦɢɰɟɥɥ. ɉȺȼ 2Amax, Ƚɫ ɚN , Ƚɫ W, ɧɫ ȽȿɆ-1 1.89 ȽȿɆ-2 14.36 41.14 14.10 ȽȿɆ-3 1.99 13.98 ȽȿɆ-4 1.78 14.00 ȽȿɆ-5 ȽȿɆ-6 40.67 1.91 ȽȿɆ-7 ȾɞɉȻ 13.70 47.89 1.36 13.68 14.81 14.46 ɂɡ ɫɩɟɤɬɪɨɜ ɗɉɊ ɬɚɤɠɟ ɛɵɥɢ ɩɨɥɭɱɟɧɵ ɡɧɚɱɟɧɢɹ aN, ɢɡɨɬɪɨɩɧɨɝɨ ɋɌ ɪɚɫɳɟɩɥɟɧɢɹ, ɜɨɡɧɢɤɚɸɳɟɝɨ ɜ ɪɟɡɭɥɶɬɚɬɟ ɜɡɚɢɦɨɞɟɣɫɬɜɢɹ ɦɚɝɧɢɬɧɵɯ ɦɨɦɟɧɬɨɜ ɧɟɫɩɚɪɟɧɧɨɝɨ ɷɥɟɤɬɪɨɧɚ ɢ ɹɞɪɚ ɚɬɨɦɚ ɚɡɨɬɚ (Ɍɚɛɥ. 1). ɂɡɜɟɫɬɧɨ, ɱɬɨ aN ɱɭɜɫɬɜɢɬɟɥɶɧɚ ɤ ɩɨɥɹɪɧɨɫɬɢ ɫɪɟɞɵ, ɨɤɪɭɠɚɸɳɟɣ ɩɚɪɚɦɚɝɧɢɬɧɵɣ ɮɪɚɝɦɟɧɬ ɡɨɧɞɚ: ɪɨɫɬ ɩɨɥɹɪɧɨɫɬɢ ɜɵɡɵɜɚɟɬ ɭɜɟɥɢɱɟɧɢɟ aN. ɂɡɦɟɧɟɧɢɟ ɩɨɥɹɪɧɨɫɬɢ ɫɪɟɞɵ ɜɨɤɪɭɝ ɩɚɪɚɦɚɝɧɢɬɧɨɝɨ ɮɪɚɝɦɟɧɬɚ ɜɧɭɬɪɢ ɦɢɰɟɥɥɵ ɧɚɢɛɨɥɟɟ ɱɚɫɬɨ ɛɵɜɚɟɬ ɫɜɹɡɚɧɨ ɫ ɩɪɨɧɢɤɧɨɜɟɧɢɟɦ ɜɨɞɵ ɜ ɨɛɥɚɫɬɶ ɝɢɞɪɨɮɨɛɧɵɯ ɰɟɩɟɣ. ɂɡ Ɍɚɛɥ.1 ɜɢɞɧɨ, ɱɬɨ ɩɪɢ ɞɨɛɚɜɥɟɧɢɢ ɞɜɭɯ ɦɟɬɢɥɟɧɨɜɵɯ ɝɪɭɩɩ ɜ ɫɩɟɣɫɟɪɧɵɣ ɦɨɫɬɢɤ (Ƚɟɦ-2 oȽɟɦ-3 ɢ Ƚɟɦ-5oȽɟɦ-6) ɜ ɫɩɟɤɬɪɟ ɗɉɊ ɢɫɱɟɡɚɸɬ ȼɒɉ, ɚ ɩɪɢ ɞɨɛɚɜɥɟɧɢɢ ɜ ɫɩɟɣɫɟɪ ɟɳɟ ɩɚɪɵ ɦɟɬɢɥɟɧɨɜɵɯ ɝɪɭɩɩ (Ƚɟɦ-3oȽɟɦ-4) ɭɦɟɧɶɲɚɟɬɫɹ ɜɪɟɦɹ ɤɨɪɪɟɥɹɰɢɢ ɜɪɚɳɟɧɢɹ, W ɫɩɢɧɨɜɨɝɨ ɮɪɚɝɦɟɧɬɚ. ɗɬɨ ɫɜɢɞɟɬɟɥɶɫɬɜɭɟɬ ɨ ɬɨɦ, ɱɬɨ ɫ ɭɜɟɥɢɱɟɧɢɟɦ ɞɥɢɧɵ ɫɩɟɣɫɟɪɧɨɝɨ ɦɨɫɬɢɤɚ ɜ ɦɨɥɟɤɭɥɚɯ ɉȺȼ ɩɨɞɜɢɠɧɨɫɬɶ ɢɯ ɭɝɥɟɜɨɞɨɪɨɞɧɵɯ ɪɚɞɢɤɚɥɨɜ ɜɨɡɪɚɫɬɚɟɬ. ɉɨ-ɜɢɞɢɦɨɦɭ, ɩɪɢ ɭɜɟɥɢɱɟɧɢɢ ɞɥɢɧɵ ɫɩɟɣɫɟɪɚ ɭɝɥɟɜɨɞɨɪɨɞɧɵɟ ɰɟɩɢ ɦɨɥɟɤɭɥ ɉȺȼ ɪɚɡɞɜɢɝɚɸɬɫɹ, ɭɜɟɥɢɱɢɜɚɹ ɫɜɨɛɨɞɧɨɟ ɩɪɨɫɬɪɚɧɫɬɜɨ, ɜ ɤɨɬɨɪɨɦ ɜɪɚɳɚɟɬɫɹ ɫɩɢɧɨɜɵɣ ɮɪɚɝɦɟɧɬ. Ɍɚɤɨɟ ɨɛɴɹɫɧɟɧɢɟ ɯɨɪɨɲɨ ɫɨɝɥɚɫɭɟɬɫɹ ɫ ɞɚɧɧɵɦɢ ɪɚɛɨɬɵ [2], Раздел 1 45 ɜ ɤɨɬɨɪɨɣ ɦɟɬɨɞɨɦ ɦɚɥɨɭɝɥɨɜɨɝɨ ɪɚɫɫɟɹɧɢɹ ɧɟɣɬɪɨɧɨɜ ɛɵɥɢ ɢɡɭɱɟɧɵ ɝɟɦɢɧɚɥɶɧɵɟ ɉȺȼ ɫ ɲɟɫɬɶɸ ɦɟɬɢɥɟɧɨɜɵɦɢ ɡɜɟɧɶɹɦɢ ɦɟɠɞɭ ɡɚɪɹɠɟɧɧɵɦɢ ɰɟɧɬɪɚɦɢ. Ȼɵɥɨ ɩɨɤɚɡɚɧɨ, ɱɬɨ ɩɪɢ ɤɨɧɰɟɧɬɪɚɰɢɢ ɦɨɥɟɤɭɥ ɉȺȼ ɜ ɪɚɫɬɜɨɪɟ 0.01Ɇ ɨɛɪɚɡɭɸɳɢɟɫɹ ɦɢɰɟɥɥɵ ɢɦɟɸɬ ɮɨɪɦɭ ɜɵɬɹɧɭɬɵɯ ɷɥɥɢɩɫɨɢɞɨɜ. ɉɪɢ ɷɬɨɦ ɫɩɟɣɫɟɪɧɚɹ ɝɪɭɩɩɚ ɫɭɳɟɫɬɜɭɟɬ ɜ ɜɢɞɟ ɪɚɫɬɹɧɭɬɨɣ ɰɟɩɢ, ɱɬɨ ɩɪɢɜɨɞɢɬ ɤ ɩɨɹɜɥɟɧɢɸ ɳɟɥɢ ɦɟɠɞɭ ɝɢɞɪɨɮɨɛɧɵɦɢ ɰɟɩɹɦɢ. Ⱥɧɚɥɢɡ ɩɚɪɚɦɟɬɪɨɜ, ɩɪɟɞɫɬɚɜɥɟɧɧɵɯ ɜ Ɍɚɛɥ.1, ɩɨɤɚɡɵɜɚɟɬ, ɱɬɨ ɝɨɥɨɜɧɵɟ ɩɨɥɹɪɧɵɟ ɝɪɭɩɩɵ ɦɨɥɟɤɭɥ ɉȺȼ ɩɪɚɤɬɢɱɟɫɤɢ ɧɟ ɨɤɚɡɵɜɚɸɬ ɜɥɢɹɧɢɹ ɧɚ ɩɨɞɜɢɠɧɨɫɬɶ ɩɚɪɚɦɚɝɧɢɬɧɨɝɨ ɮɪɚɝɦɟɧɬɚ ɜɧɭɬɪɢ ɦɢɰɟɥɥ, ɧɨ ɜɥɢɹɸɬ ɧɚ ɦɢɤɪɨɩɨɥɹɪɧɨɫɬɶ ɟɝɨ ɨɤɪɭɠɟɧɢɹ. ɇɚɩɪɢɦɟɪ, ɡɚɦɟɧɚ ɦɟɬɢɥɶɧɨɣ ɝɪɭɩɩɵ ɧɚ ɷɬɢɥɶɧɭɸ (Ƚɟɦ-1oȽɟɦ-3) ɢɥɢ ɩɢɩɟɪɢɞɢɥɶɧɭɸ (Ƚɟɦ-1oȽɟɦ-6), ɫɨɡɞɚɟɬ ɞɨɩɨɥɧɢɬɟɥɶɧɵɟ ɩɪɟɩɹɬɫɬɜɢɹ ɞɥɹ ɩɪɨɧɢɤɧɨɜɟɧɢɹ ɦɨɥɟɤɭɥ ɜɨɞɵ ɜɧɭɬɪɶ ɦɢɰɟɥɥɵ, ɱɬɨ ɩɪɨɹɜɥɹɟɬɫɹ ɜ ɫɩɟɤɬɪɚɯ ɗɉɊ ɤɚɤ ɡɚɦɟɬɧɨɟ ɭɦɟɧɶɲɟɧɢɟ ɜɟɥɢɱɢɧɵ ɚN. ȼɜɟɞɟɧɢɟ ɜ ɫɩɟɣɫɟɪɧɵɣ ɦɨɫɬɢɤ ɝɪɭɩɩɵ NH- (Ƚɟɦ-1oȽɟɦ-7) ɩɪɢɜɨɞɢɬ ɤ ɞɨɫɬɚɬɨɱɧɨ ɩɥɨɬɧɨɣ ɭɩɚɤɨɜɤɟ ɦɨɥɟɤɭɥ ɉȺȼ ɜ ɨɛɥɚɫɬɹɯ, ɨɤɪɭɠɚɸɳɢɯ ɩɚɪɚɦɚɝɧɢɬɧɵɣ ɮɪɚɝɦɟɧɬ !N x O ɜɧɭɬɪɢ ɦɢɰɟɥɥ (ɪɟɡɭɥɶɬɚɬɨɦ ɹɜɥɹɟɬɫɹ ɡɚɦɟɬɧɨ ɜɨɡɪɨɫɲɚɹ ɜɟɥɢɱɢɧɚ 2Amax). ɗɬɨ ɦɨɠɟɬ ɛɵɬɶ ɫɜɹɡɚɧɨ ɫ ɢɡɦɟɧɟɧɢɟɦ ɤɨɧɮɨɪɦɚɰɢɢ ɫɩɟɣɫɟɪɚ, ɩɪɢɜɨɞɹɳɟɟ ɤ ɫɨɤɪɚɳɟɧɢɸ ɩɪɨɫɬɪɚɧɫɬɜɚ ɦɟɠɞɭ ɝɢɞɪɨɮɨɛɧɵɦɢ ɰɟɩɹɦɢ ɦɨɥɟɤɭɥ ɉȺȼ, ɜ ɤɨɬɨɪɨɦ ɜɪɚɳɚɸɬɫɹ ɫɩɢɧɨɜɵɟ ɮɪɚɝɦɟɧɬɵ. Ɂɧɚɱɟɧɢɟ aN ɞɥɹ ɫɢɫɬɟɦɵ ɫ Ƚɟɦ-7, ɜɨɡɪɨɫɲɟɟ ɩɨ ɫɪɚɜɧɟɧɢɸ ɫ ɨɫɬɚɥɶɧɵɦɢ ɨɛɪɚɡɰɚɦɢ, ɫɜɢɞɟɬɟɥɶɫɬɜɭɟɬ ɨɛ ɭɜɟɥɢɱɟɧɢɢ ɦɢɤɪɨɩɨɥɹɪɧɨɫɬɢ ɫɪɟɞɵ, ɨɤɪɭɠɚɸɳɟɣ ɝɪɭɩɩɭ !N x O. ɗɬɨ ɦɨɠɧɨ ɨɛɴɹɫɧɢɬɶ ɨɛɪɚɡɨɜɚɧɢɟɦ ɜɨɞɨɪɨɞɧɵɯ ɫɜɹɡɟɣ ɦɟɠɞɭ NH-ɝɪɭɩɩɨɣ ɫɩɟɣɫɟɪɧɨɝɨ ɦɨɫɬɢɤɚ ɢ ɥɢɛɨ ɦɨɥɟɤɭɥɚɦɢ ɜɨɞɵ, ɥɢɛɨ ɫɩɢɧɨɜɵɦ ɮɪɚɝɦɟɧɬɨɦ ɡɨɧɞɚ. Ɇɢɰɟɥɥɵ, ɨɛɪɚɡɨɜɚɧɧɵɟ ȾɞɉȻ, ɫɨɞɟɪɠɚɳɢɦ ɨɞɧɭ ɝɢɞɪɨɮɨɛɧɭɸ ɰɟɩɶ, ɨɛɥɚɞɚɸɬ ɛɨɥɟɟ ɪɵɯɥɨɣ ɭɩɚɤɨɜɤɨɣ ɢ, ɤɚɤ ɫɥɟɞɫɬɜɢɟ, ɛɨɥɶɲɟɣ ɩɨɞɜɢɠɧɨɫɬɶɸ ɦɨɥɟɤɭɥ ɉȺȼ ɜ ɩɪɢɩɨɥɹɪɧɨɦ ɫɥɨɟ ɦɢɰɟɥɥɵ, ɱɟɦ ɟɝɨ «ɞɜɭɯɜɨɫɬɧɵɟ» ɚɧɚɥɨɝɢ (Ɍɚɛɥ.1). Ɍɚɤɚɹ ɭɩɚɤɨɜɤɚ, ɜɟɪɨɹɬɧɨ, ɹɜɥɹɟɬɫɹ ɬɚɤɠɟ ɩɪɢɱɢɧɨɣ ɬɨɝɨ, ɱɬɨ «ɨɛɜɨɞɧɟɧɧɨɫɬɶ» ɷɬɢɯ ɨɛɥɚɫɬɟɣ ɦɢɰɟɥɥɵ ɞɥɹ ȾɞɉȻ ɛɨɥɶɲɟ, ɱɟɦ ɞɥɹ ɝɟɦɢɧɚɥɶɧɵɯ ɉȺȼ 1-6, ɨ ɱɟɦ ɫɜɢɞɟɬɟɥɶɫɬɜɭɸɬ ɢɡɦɟɧɟɧɢɹ ɜɟɥɢɱɢɧɵ aN. Ʌɢɬɟɪɚɬɭɪɚ 1. Zuev Yu.F., Vylegzhanina N.N., Zakhartchenko N.L.// Appl.Magn.Reson. 2003.V.25,P.29-42. 2. Aswal V.K., De S., Goyal P.S., Bhattacharya S., Heenan R.K.// Phys.Rev. E. 1998.V.57,P.776-783.