. 2015. 1. . 193–196. DOI: 10.14258/jcprm.201501545 676.15.017.6 © * . , . « », ., 606000 ( , 7, ), e-mail: olga_vdovina@skif.ru . . , , . - , . . ( ) . : , , , , , , , , , , , , - . ( ) , , [1–5]. 60- . XX . - . . [6, 7], - . . « – », - , : , , , , , , - . . . , , . – , e-mail: olga_vdovina@skif.ru – , e-mail: skif.special.chemicals@gmail.com , * , - , . , , ) ) , , . - 194 . , , . , 1, , : . - . 1, , . , , , - . ( ). : – 40–60 ; . – – , ; - 70°. : , . , 1: 2: 3: – -2 10 . = 22,85, µ = 156,0, G = 1,033, = 2,98 = 19,25, µ = 44,5, G = 1,022, = 3,00 = 21,76, µ = 53,0, G = 1,028, = 3,07 , %; G – ( 3 , ;µ– , ): (1 = ). , [8]. - , cos 2 2 2 h /(d/2) + h . = (d/2)2 – 2. 10, 100 1000 ; 1 , ; , . . H H2 C C COOC6H5 I II III H H2 C H H2 C C C OCOCH2CH2NH(CH3)2 COO(CH2)17CH3 IV . 1. III – V ; IV – :I– ;V– ; II – ; . 2. : d– – , , ;h– .; , - ,% 1 22,85 ( .) 2,285 0,2285 0,02285 19,25 ( .) 1,925 0,1925 0,01925 21,76 ( .) 2,176 0,2176 0,02176 2 3 195 ... ° cos d h 6,8 6,9 7,5 2,2 2,1 1,6 0,4098 0,4592 0,6919 66 62 46 6,4 6,3 7,2 2,7 2,7 1,8 0,1683 0,1528 0,6000 80 81 53 6,4 6,4 7,1 2,5 2,6 1,8 0,1528 0,2047 0,5909 81 78 54 3, 62–66°). 2 2 3 , 3 ( . 3– , 78–81°, 10 – 100 2 26–28° ( . 3), 0 78–81°), – , 1– , - 1( 70°. 62–66°, 2 - 1000 1 80°, 20°. - . . , ( 2 . 3 ) . ( 30000–60000 , . ). ( ) [9]. , . . . . , : , - , . , , . , 1, - . , - . , . - . 1. , . , , - . 2. 3 , . 3. 32 . – 3 . 80°, - 196 . 1. 2. 3. 4. ., . . . . ., ., , . . ., 2006. 696 . ., 1988. 440 . . . ., 1987. 288 . // : 5. VII . - .- . . // : 6. 7. 8. 9. , 2007. . 141. . , 2006. . 2. . 283-285. . . . VI . .- . . ., 1968. 80 . . ., 2008. 52 . / . . . . ., 1986. 216 . Patent 2009/0068485 (US). Cationic surface sizingagent and newsprint paper / K. Inaoka, T. Nakata, Y. Hashiguchi. 2009. 12 s. 18 14 2014 . 2015 . Vdovina O.S.*, Kozhevnikov S.Iu. DEVELOPMENT OF POLYMER POLYCATIONIC ADHESIVE SURFACE SIZING PAPER Co.Ltd «SKIF Special Chemical», Vostochnaya promzona, 7, Dzerzhinsk, Nizhny Novgorod region, 606000 (Russia), e-mail: olga_vdovina@skif.ru The article contains a study on the development of a polycationic polymer adhesive surface sizing of paper. The problems study the chemical composition of the polymer, based on the properties required. The analysis of the monomers and defined-Leno that the polymer should be linear, and received a number of alkene polymerization of acrylic derivatives. The macromolecular flails must contain sufficient cationic, hydrophilic and hydrophobic functional groups and radicals. A tentative chemical structure of macromolecular chain links. The characteristics of the synthesized polymer products (adhesives) and the study of their hydrophobicity. Keywords: paper, surface sizing, hydrophobicity, hydrophilicity, a polymer, a copolymer, a polycationic polymer, starch macromolecule, macromolecular chain derived from acrylic acid structural units, the contact angle. References 1. 2. 3. 4. 5. 6. 7. 8. 9. Krylatov Iu.A., Koverninskii I.N. Prokleika bumagi. [Paper sizing]. Moscow, 1987, 288 p. (in Russ.). Ivanov S.N. Tekhnologiia bumagi. [Technology papers]. Moscow, 2006, 696 p. (in Russ.). Fliate D.M. Tekhnologiia bumagi. [Technology papers]. Moscow, 1988, 440 p. (in Russ.). Gorzhanov V.V., Temruk V.I., Solov'eva T.V. Energo- i materialosberegaiushchie ekologicheski chistye tekhnologii: tezisy dokladov VII mezhdunar. nauch.-tekhn. konf. [Energy and material-clean technology: abstracts of the VII International Scientific and Technical Conference]. Grodno, 2007, p. 141. (in Russ.). Solov'eva T.V. Energo- i materialosberegaiushchie ekologicheski chistye tekhnologii: tezisy dokladov VI mezhdunar. nauch.-tekhn. konf. [Energy and material-clean technology: abstracts of the VI International Scientific and Technical Conference]. Grodno, 2006, part 2, pp. 283–285. (in Russ.). Petrov A.P. Poverkhnostnaia prokleika bumagi i kartona. [Surface sizing of paper and paperboard]. Moscow, 1968, 80 p. (in Russ.). Kopyl'tsov A.A. Primenenie krakhmala v proizvodstve bumagi i kartona. [The use of starch in the manufacture of paper and paperboard]. Moscow, 2008, 52 p. (in Russ.). Laboratornye raboty i zadachi po kolloidnoi khimii. [Laboratory work and objectives of colloid chemistry]. Ed. Iu.G. Frolov, A.S. Grodskii. Moscow, 1986, 216 p. (in Russ.). Patent 2009/0068485 (US). 2009. Received December 18, 2014 Revised January 14, 2015 * Corresponding author.
