Ðåäàêöèÿ: 14/04/2011 ËÈÑÒ ÄÀÍÍÛÕ ÁÅÇÎÏÀÑÍÎÑÒÈ 1 Ìàðêèðîâêà âåùåñòâà (èëè ïðåïàðàòà) è ïîñòàâùèêà Íàçâàíèå ïðîäóêòà: ¹ ëèñòêà òåõíè÷åñêèõ äàííûõ: Èñïîëüçîâàíèå âåùåñòâà/ïðåïàðàòà: Êîä ïðîäóêòà: Field 1: Field 2: Field 3: Íàçâàíèå ïîñòàâùèêà: Àäðåñ ïîñòàâùèêà: Òåëåôîí: Ôàêñ: Îòâåòñòâåííîå ëèöî: Email: Òåëåôîí ýêñòðåííîé ïîìîùè: 777226 2. 0. 1 Multi-purpose, aqueous cleaner. 777226 (25Ltr plastic) Wilhelmsen Ships Service AS Strandveien 20, N1324 Lysaker, Norway Tel: (+47) 67 58 45 50 Wilhelmsen Ships Service AS Willem Barentszstraat 50 3165AB Rotterdam The Netherlands +31 10 4877 777 +31 10 4877 888 Patrick Rijsdijk, Product HSE Manager,Tel.:+31 6 349 440 35 [email protected] **ONLY TO BE USED IN CASE OF AN INCIDENT** NCEC: +44 1865 407333, CHEMTREC (800) 424 9300 American Chemistry Council +1 703 527 3887, Greece +30 210 7793777 2 Îïðåäåëåíèå èñòî÷íèêîâ îïàñíîñòè Åäêèé - Çàïàõ: Áåç çàïàõà - Âíåøíèé âèä: Æèäêîñòü, ïðîçðà÷íîå, Æåëòîãî öâåòà - Ïîïàäàíèå â ãëàçà: Âûçûâàåò ðàçúåäàíèå ñëèçèñòîé îáîëî÷êè ãëàç, Ìîæåò âûçâàòü çàáîëåâàíèÿ ãëàç - Ïîïàäàíèå íà êîæó: Âûçûâàåò îæîãè (R34) - Âäûõàíèå: Ìîæåò âûçâàòü ðàçäðàæåíèå - Ïðîãëàòûâàíèå: Not regarded as a potential route of exposure., Ìîæåò âûçâàòü çàáîëåâàíèÿ ñëèçèñòîé æåëóäêà, Ïðîãëàòûâàíèå â çíà÷èòåëüíûõ êîëè÷åñòâàõ ìîæåò ïðèâåñòè ê ïîâðåæäåíèþ ñëèçèñòûõ îáîëî÷åê Êëàññèôèêàöèÿ âåùåñòâà èëè ïðåïàðàòà - Counsil Directive 1999/45/EEC Classification, packing and labelling of dangerous preparations. Ôàêòîðû îïàñíîñòè - Âûçûâàåò îæîãè (R34) Ôàêòîðû áåçîïàñíîñòè -  ñëó÷àå ïîïàäàíèÿ â ãëàçà íåìåäëåííî ïðîìûòü áîëüøèì êîëè÷åñòâîì âîäû è îáðàòèòüñÿ ê âðà÷ó (S26) - Íàäåòü ñîîòâåòñòâóþùóþ çàùèòíóþ ñïåöîäåæäó, çàùèòíûå ñðåäñòâà äëÿ ãëàç/ëèöà è ïåð÷àòêè (S36/37/39) - Ïðè íåñ÷àñòíîì ñëó÷àå èëè åñëè âû ïî÷óâñòâîâàëè íåäîìîãàíèå, íåìåäëåííî îáðàòèòåñü ê âðà÷ó (ïîêàæèòå ýòèêåòêó, åñëè âîçìîæíî) (S45) 1 NALFLEET ALKALINE CLEANER 79105 Ðåäàêöèÿ: 14/04/2011 3 Ñîñòàâ/äàííûå î êîìïîíåíòàõ Õèìè÷åñêîå íàçâàíèå Êîíöåíòðàöèÿ ¹ ïî CAS ¹ ÅÑ Ôàêòîðû îïàñíîñòè* Îáîçíà÷åí potassium hydroxide 1-5 % 1310-58-3 215-181-3 R22, 35 C Disodiummetasilicate 1-5 % 6834-92-0 229-912-9 R34, 37 C Fatty alcohol ethoxylates 1-5 % 34398-01-1 500-084-3 R22, 41 Xn 2-(2-butoxyethoxy)ethanol 1-5 % 112-34-5 203-961-6 R36 Xi *Ñì. ðàçäåë ¹ 16 4 Ìåðû ïî îêàçàíèþ íåîòëîæíîé ïîìîùè Ïîïàäàíèå íà êîæó - Íåìåäëåííî ñíÿòü çàãðÿçíåííóþ îäåæäó è îáèëüíî ñìî÷èòü ïîðàæåííûå ó÷àñòêè êîæè âîäîé. Çàòåì ïðîìûòü âîäîé ñ ìûëîì - Åñëè ó âàñ âîçíèêëè ñîìíåíèÿ èëè ñèìïòîìû íå ïðîõîäÿò, îáðàòèòåñü ê âðà÷ó Ïîïàäàíèå â ãëàçà - Åñëè âåùåñòâî ïîïàëî â ãëàçà, íåìåäëåííî ïðîìûòü áîëüøèì êîëè÷åñòâîì âîäû íå ìåíåå 15 ìèíóò - Ïîäíèìàÿ âåêè, òùàòåëüíî ïðîìûòü ãëàçà - Ïîëó÷èòü íåîòëîæíóþ ìåäèöèíñêóþ ïîìîùü Ïðîãàëàòûâàíèå - ÏÐÈ ÏÐÎÃËÀÒÛÂÀÍÈÈ: Ïðîïîëîñêàòü ðîò. ÍÅ âûçûâàòü ðâîòó. - Äàòü âûïèòü âîäû èëè ìîëîêà - Íè â êîåì ñëó÷àå íå âûçûâàòü ðâîòó è íå äàâàòü æèäêîñòè ïîñòðàäàâøåìó, íàõîäÿùåìóñÿ áåç ñîçíàíèÿ - Ïîëó÷èòü íåîòëîæíóþ ìåäèöèíñêóþ ïîìîùü Âäûõàíèå - ÏÐÈ ÂÄÛÕÀÍÈÈ: Ïðè çàòðóäíåííîì âäûõàíèè âûíåñòè ïîñòðàäàâøåãî íà ñâåæèé âîçäóõ è îáåñïå÷èòü åìó ïîëíûé ïîêîé â óäîáíîì äëÿ äûõàíèÿ ïîëîæåíèè. - Åñëè ó âàñ âîçíèêëè ñîìíåíèÿ èëè ñèìïòîìû íå ïðîõîäÿò, îáðàòèòåñü ê âðà÷ó 5 Ìåðû ïðîòèâîïîæàðíîé áåçîïàñíîñòè - Íå îãíåîïàñíî.  ñëó÷àå ïîæàðà èñïîëüçîâàòü îãíåòóøàùèå ñðåäñòâà, îòâå÷àþùèå îêðóæàþùèì óñëîâèÿì - Íàäåòü êîñòþì ïðîòèâîõèìè÷åñêîé çàùèòû è èçîëèðóþùèé ïðîòèâîãàç ïîëîæèòåëüíîãî äàâëåíèÿ 6 Ìåðû ïî ïðåäîòâðàùåíèþ ñëó÷àéíîãî âûáðîñà Ìåðû ëè÷íîé ïðåäîñòîðîæíîñòè, èíäèâèäóàëüíûå ñðåäñòâà çàùèòû è ïîðÿäîê äåéñòâèé â àâàðèéíîé îáñòàíîâêå - Íàäåòü çàùèòíóþ îäåæäó êàê óêàçàíî â ðàçäåëå 8 - Òùàòåëüíî âûìûòü ïîñëå êîíòàêòà ñ ðàçëèòûì âåùåñòâîì Ýêîëîãè÷åñêèå ìåðû ïðåäîñòîðîæíîñòè - Íå äîïóñòèòü ïîïàäàíèÿ â êîëëåêòîð ãîðîäñêîé êàíàëèçàöèîííîé ñåòè è âîäîñòîêè - Íå ñìûâàòü ðàçëèâøèéñÿ ìàòåðèàë â ãîðîäñêèå ñèñòåìû âîäîñíàáæåíèÿ Ìåòîäû è ìàòåðèàëû, èñïîëüçóåìûå äëÿ ëîêàëèçàöèè è î÷èñòêè - Îñòàíîâèòü óòå÷êó áåçîïàñíûì îáðàçîì. - Àáñîðáèðîâàòü óòå÷êó çåìëåé èëè ïåñêîì 2 NALFLEET ALKALINE CLEANER 79105 Ðåäàêöèÿ: 14/04/2011 6 Ìåðû ïî ïðåäîòâðàùåíèþ ñëó÷àéíîãî âûáðîñà (....) - Ïðîâåòðèòü ðàáî÷óþ çîíó è âûìûòü ïëîùàäêó, íà êîòîðóþ ðàçëèëàñü æèäêîñòü, ïîñëå óäàëåíèÿ ìàòåðèàëà 7 Ïîãðóçêà è õðàíåíèå Ìåðû ïðåäîñòîðîæíîñòè ïðè ðàáîòå - Èçáåãàòü ïîïàäàíèÿ íà êîæó è â ãëàçà (S24/25) - Èìåòü â íàëè÷èè áóòûëêè ñ ïðîìûâêîé äëÿ ãëàç Óñëîâèÿ áåçîïàñíîãî õðàíåíèÿ, âêëþ÷àÿ íåñîâìåñòèìûå ìàòåðèàëû - Õðàíèòü â ïëîòíî çàêðûòîé òàðå â ïðîõëàäíîì, õîðîøî ïðîâåòðèâàåìîì ïîìåùåíèè (S3/7/9) - Ïðåäîõðàíÿòü îò âîçäåéñòâèÿ íèçêèõ òåìïåðàòóð 8 Ïðåäîòâðàùåíèå âîçäåéñòâèÿ íà îðãàíèçì è èíäèâèäóàëüíûå ñðåäñòâà çàùèòû Êîíòðîëèðóåìûå ïàðàìåòðû - potassium hydroxide WEL (êðàòêîâðåìåííî) 2 ìã/ì3 - 2-(2-butoxyethoxy)ethanol WEL (äëèòåëüíî) 68 ìã/ì3 Ìåðû çàùèòû îò âîçäåéñòâèÿ - Ñïåöèàëüíîé âåíòèëÿöèè íå òðåáóåòñÿ, åñëè ïðîäóêò íå èñïîëüçóåòñÿ â ðàñïûëåííîì âèäå Ìåðû ïî çàùèòå îò âîçäåéñòâèÿ íà ðàáî÷åì ìåñòå - Íàäåòü î÷êè, îáåñïå÷èâàþùèå ïîëíóþ çàùèòó ãëàç - Íàäåòü ñîîòâåòñòâóþùóþ çàùèòíóþ ñïåöîäåæäó, âêëþ÷àÿ çàùèòíûå ñðåäñòâà äëÿ ãëàç/ëèöà è ïåð÷àòêè (ðåêîìåíäóþòñÿ íåîïðåíîâûå èëè íèòðèëîâûå) - Ïðè îòñóòñòâèè òóìàíà âåùåñòâà çàùèòà îðãàíîâ äûõàíèÿ íå òðåáóåòñÿ Ïåð÷àòêè Êîñòþì Î÷êè 9 Ôèçè÷åñêèå è õèìè÷åñêèå ñâîéñòâà - Çàïàõ: Áåç çàïàõà - Âíåøíèé âèä: Æèäêîñòü, ïðîçðà÷íîå, Æåëòîãî öâåòà - pH 13-14 - Ïîëíîñòüþ ðàñòâîðèìî â âîäå - Ïëîòíîñòü 1.045 - 1.055 ã/ñì3 ïðè 20 °C 10 Ñòàáèëüíîñòü è ðåàêòèâíîñòü - Ýòîò ïðîäóêò ñ÷èòàåòñÿ ñòàáèëüíûì ïðè íîðìàëüíûõ óñëîâèÿõ Íåñîâìåñòèì ñ êèñëîòîé 11 Òîêñèêîëîãè÷åñêàÿ èíôîðìàöèÿ Èíôîðìàöèÿ î òîêñèêîëîãè÷åñêîì äåéñòâèè - ËÄ50 (ïåðîðàëüíî, êðûñà) (Surfactants) >2000 ìã/êã 3 NALFLEET ALKALINE CLEANER 79105 Ðåäàêöèÿ: 14/04/2011 11 Òîêñèêîëîãè÷åñêàÿ èíôîðìàöèÿ (....) Âäûõàíèå - Ïàðû èëè àýðîçîëè ìîãóò âûçûâàòü ðàçäðàæåíèå ñëèçèñòûõ îáîëî÷åê ãëàç, íîñà è äûõàòåëüíûõ ïóòåé Ïîïàäàíèå íà êîæó - Âûçûâàåò ñåðüåçíûå îæîãè êîæè è ïîâðåæäåíèÿ ãëàç Ïîïàäàíèå â ãëàçà - Ìîæåò âûçâàòü çàáîëåâàíèÿ ãëàç Ïðîãàëàòûâàíèå - Íå ðàññìàòðèâàåòñÿ â êà÷åñòâå ïîòåíöèàëüíîãî ïóòè ïðîÿâëåíèÿ. - Ïðîãëàòûâàíèå â çíà÷èòåëüíûõ êîëè÷åñòâàõ ìîæåò ïðèâåñòè ê ïîâðåæäåíèþ ñëèçèñòûõ îáîëî÷åê 12 Ýêîëîãè÷åñêàÿ èíôîðìàöèÿ Ýêîòîêñè÷íîñòü - Ýòîò ïðîäóêò íå ñîäåðæèò èíãðåäèåíòîâ, êëàññèôèöèðóåìûõ â ÅÑ êàê îïàñíûå äëÿ îêðóæàþùåé ñðåäû. - ËÊ50 (ðûáà) (Fatty alcohol ethoxylate) 1-10 ìã/ë (96 ÷) - ËÊ50 (ðûáà) (2-(2-Buthoxyethoxy)ethanol) >100 ìã/ë (96 ÷) - Biodegradability. OECD-test. 28 days 20% Diethylhydroxylamine - Biodegradability. OECD-test. 28 days 20% Diethylhydroxylamine Ïîäâèæíîñòü â ïî÷âå - Ïîëíîñòüþ ðàñòâîðèìî â âîäå 13 Ðåêîìåíäàöèè ïî óòèëèçàöèè Ìåòîäû óòèëèçàöèè îòõîäîâ - Óäàëåíèå îòõîäîâ äîëæíî ïðîâîäèòüñÿ â ñîîòâåòñòâèè ñ ìåñòíûì, ãîñóäàðñòâåííûì èëè íàöèîíàëüíûì çàêîíîäàòåëüñòâîì - Íå ñáðàñûâàòü â êàíàëèçàöèþ èëè â îêðóæàþùóþ ñðåäó, äëÿ óíè÷òîæåíèÿ ñäàâàòü íà ñïåöèàëüíûé ïóíêò ñáîðà îòõîäîâ Êëàññèôèêàöèÿ - Êëàññ çàãðÿçíåíèÿ ÅÑ: 06-02 14 Èíôîðìàöèÿ î òðàíñïîðòèðîâêå Êîððîçèéíîå Ïîëíîå íàèìåíîâàíèå ãðóçà: CAUSTIC ALKALI LIQUID, N.O.S. (Potassium hydroxide, Disodiummetasilicate) UN Ïîëíîå íàèìåíîâàíèå ãðóçà: ¹ UN: Ãðóïïà óïàêîâêè: CAUSTIC ALKALI LIQUID, N.O.S. (Potassium hydroxide, Disodiummetasilicate) UN1719 Êëàññ îïàñíîñòè: III 4 8 NALFLEET ALKALINE CLEANER 79105 Ðåäàêöèÿ: 14/04/2011 14 Èíôîðìàöèÿ î òðàíñïîðòèðîâêå (....) Íàçåìíûé/æåëåçíîäîðîæíûé (ADR/RID) Ïîëíîå íàèìåíîâàíèå ãðóçà: ¹ ADR UN: Ïîäðèñê ADR: CAUSTIC ALKALI LIQUID, N.O.S. (Potassium hydroxide, Disodiummetasilicate) UN1719 Êëàññ îïàñíîñòè ADR: Òåìïåðàòóðà âîñïëàìåíåíèÿ ADR: 8 - CAUSTIC ALKALI LIQUID, N.O.S. (Potassium hydroxide, Disodiummetasilicate) UN1719 Êëàññ îïàñíîñòè IMDG: III IMDG EmS (àâàðèéíûå ãðàôèêè): Òåìïåðàòóðà âîñïëàìåíåíèÿ IMDG: 8 F-A, S - Ìîðñêîé (IMDG) Ïîëíîå íàèìåíîâàíèå ãðóçà: ¹ IMDG UN: Ãðóïïà óïàêîâêè IMDG: Ïîäðèñê IMDG: Âîçäóøíûé (ICAO/IATA) Ïîëíîå íàèìåíîâàíèå ãðóçà: ¹ ICAO Un: Ãðóïïà óïàêîâêè ICAO: Òåìïåðàòóðà âîñïëàìåíåíèÿ ICAO: CAUSTIC ALKALI LIQUID, N.O.S. (Potassium hydroxide, Disodiummetasilicate) UN1719 Êëàññ îïàñíîñòè ICAO: III Ïîäðèñê ICAO: - 8 - DOT / CFR (US Department of Transportation) DOT Proper Shipping Name: Îïàñíûé ìàòåðèàë: Êëàññ îïàñíîñòè: RQ ïðîäóêòà (ôóíò): DOT Flashpoint: CORROSIVE LIQUID, N.O.S (Sodium Hydroxide, Sodium Metasilicate solution) Potassium hydroxide, Disodiummetasilicate UN171 8 Èäåíòèôèêàöèîííûé íîìåð: Ïîäðèñê DOT: - 15 Íîðìàòèâíàÿ èíôîðìàöèÿ Êëàññèôèêàöèÿ è ìàðêèðîâêà - Counsil Directive 1999/45/EEC Classification, packing and labelling of dangerous preparations. - Ñì. Äèðåêòèâó îòíîñèòåëüíî îáðàùåíèÿ ñ îïàñíûìè âåùåñòâàìè (67/548/EEC) Äèðåêòèâû è çàêîíîäàòåëüíûå íîðìû ïî îõðàíå òðóäà, òåõíèêå áåçîïàñíîñòè è îõðàíå îêðóæàþùåé ñðåäû, êàñàþùèåñÿ âåùåñòâà èëè ïðåïàðàòà - This Safety Data Sheet has been prepared in accordance with article 31 and annex II in REACH and Directive 453/2010/EU. - Èíôîðìàöèÿ ïî ñîñòàâó äåòåðãåíòîâ â ñîîòâåòñòâèè ñ Ïðàâèëîì (ÅÑ) ¹ 648/2004 Åâðîïåéñêîãî Ïàðëàìåíòà è Ñîâåòà Åâðîïû: - Íåèîííûå ïîâåðõíîñòíî-àêòèâíûå âåùåñòâà 5-15 % - Àìôîòåðíûå ïîâåðõíîñòíî-àêòèâíûå âåùåñòâà <5 % 16 Äðóãàÿ èíôîðìàöèÿ Òåêñò êîäîâ ôîðìóëèðîâîê R è S, èñïîëüçóåìûõ â ýòîì ëèñòå äàííûõ áåçîïàñíîñòè:R22: Âðåäåí ïðè ïðîãëàòûâàíèè; R34: Âûçûâàåò îæîãè; R35: Âûçûâàåò ñèëüíûå îæîãè; R36: Âûçûâàåò ðàçäðàæåíèÿ ãëàç; R37: Âûçûâàåò ðàçäðàæåíèå äûõàòåëüíîé ñèñòåìû; R41: Îïàñíîñòü ñåðüåçíûõ ïîâðåæäåíèé ãëàç. Ïðåäñòàâëåííûå çäåñü äàííûå îñíîâàíû íà òåêóùèõ çíàíèÿõ è îïûòå.  ýòîì ëèñòå äàííûõ áåçîïàñíîñòè îïèñàí ïðîäóêò ñ òî÷êè çðåíèÿ òðåáîâàíèé áåçîïàñíîñòè, ëèñò äàííûõ áåçîïàñíîñòè íå äàåò íèêàêèõ ãàðàíòèé îòíîñèòåëüíî ñâîéñòâ ïðîäóêòà. 5 NALFLEET ALKALINE CLEANER 79105 Ðåäàêöèÿ: 14/04/2011 16 Äðóãàÿ èíôîðìàöèÿ (....) Ïðåäñòàâëåííûå çäåñü äàííûå âåðíû òîëüêî â ñëó÷àå ñîîòâåòñòâóþùåãî èñïîëüçîâàíèÿ ïðîäóêòà. Ïðîäóêò íå ïðîäàåòñÿ â êà÷åñòâå ïîäõîäÿùåãî äëÿ äðóãèõ öåëåé - òàêîå èñïîëüçîâàíèå ìîæåò ïðèâåñòè ê ðèñêàì, íå óêàçàííûì â äàííîì ëèñòå. Çàïðåùàåòñÿ èñïîëüçîâàíèå â äðóãèõ öåëÿõ áåç êîíñóëüòàöèè ñ ïðîèçâîäèòåëåì. Èíôîðìàöèÿ, ïðåäîñòàâëåííàÿ î ïðîäóêòå â äàííîì ëèñòå äàííûõ áåçîïàñíîñòè, îñíîâàíà íà çíàíèè ñâîéñòâ îòäåëüíûõ êîìïîíåíòîâ 6