Свидетельства магматогенного происхождения

RMS DPI 2008-1-84-0
http://www.minsoc.ru/2008-1-84-0
ɋɜɢɞɟɬɟɥɶɫɬɜɚ ɦɚɝɦɚɬɨɝɟɧɧɨɝɨ ɩɪɨɢɫɯɨɠɞɟɧɢɹ ɪɭɞɨɨɛɪɚɡɭɸɳɢɯ
ɮɥɸɢɞɨɜ ɧɚ Mo-U ɦɟɫɬɨɪɨɠɞɟɧɢɹɯ ɋɬɪɟɥɶɰɨɜɫɤɨɝɨ ɪɭɞɧɨɝɨ ɩɨɥɹ
(ȼɨɫɬ. Ɂɚɛɚɣɤɚɥɶɟ, Ɋɨɫɫɢɹ)
Ʉɪɵɥɨɜɚ Ɍ.Ʌ.1, Ⱥɥɟɲɢɧ Ⱥ.ɉ.1, Ʌɨɦɦ Ɍ.2, ȼɟɥɢɱɤɢɧ ȼ.ɂ.1, Ʉɸɧɟ Ɇ.2
1
ɂȽȿɆ ɊȺɇ, Ɇɨɫɤɜɚ, Ɋɨɫɫɢɹ [email protected]
2
Ʌɚɛɨɪɚɬɨɪɢɹ UMR7566 (G2R) ɭɧɢɜɟɪɫɢɬɟɬɚ Ⱥ. ɉɭɚɧɤɚɪɟ, ɇɚɧɫɢ, Ɏɪɚɧɰɢɹ
Evidences of magmatic genesis of ore-forming fluids in the Mo-U deposits of
the Stretsovsky ore field (Transbaikalia, Russia)
Krylova T. L.1, Aleshin A.P.1, Lhomme T 2, Velichkin V. I.1, Cuney M.2
1
IGEM RAS, Moscow, Russia, [email protected]
2
CREGU-UMR7566 Universite Henri Poincare, Nancy, France
The results of fluid inclusion studies based on detailed mineralogical investigations
allowed to conclude that mineralization of uranium ore stage began to precipitate in the
temperature range of 500-530oC. At the temperature about 400oC the state of fluids was close to
critical. Deposition of primary brannerite-pitchblende ores occurred at the temperature decrease
down to 350-300oC from Na-(HCO3)-Cl water fluids. Redeposition of primary ores occurred in
the temperature range of 390-160oC and was not essentually separated in time from ore
deposition. Carbon dioxide and bicarbonate-ion were not significant in ore formation.
Presumably, ore forming fluids had magmatic origin, uranium was transported as fluoride (or
chloride) U4+ complexes, and uranium precipitated at the temperature barrier.
ɋɬɪɟɥɶɰɨɜɫɤɨɟ ɭɪɚɧɨɜɨ-ɪɭɞɧɨɟ ɩɨɥɟ ɭɧɢɤɚɥɶɧɨ ɩɨ ɡɚɩɚɫɚɦ ɭɪɚɧɚ ɢ ɝɟɨɥɨɝɢɱɟɫɤɨɦɭ
ɩɨɥɨɠɟɧɢɸ. Ⱦɟɜɹɬɧɚɞɰɚɬɶ Ɇɨ-U ɦɟɫɬɨɪɨɠɞɟɧɢɣ ɪɚɫɩɨɥɨɠɟɧɵ ɜ ɩɪɟɞɟɥɚɯ ɤɚɥɶɞɟɪɵ
ɞɢɚɦɟɬɪɨɦ 15 ɤɦ. Ɉɛɳɢɟ ɡɚɩɚɫɵ ɭɪɚɧɚ ɫɨɫɬɚɜɥɹɸɬ ɨɤɨɥɨ 250 ɬɵɫ. ɬɨɧɧ. ɍɫɥɨɜɢɹ
ɨɛɪɚɡɨɜɚɧɢɹ ɭɪɚɧɨɜɵɯ ɦɟɫɬɨɪɨɠɞɟɧɢɣ ɋɬɪɟɥɶɰɨɜɫɤɨɝɨ ɪɭɞɧɨɝɨ ɩɨɥɹ ɢɡɭɱɚɥɢɫɶ ɦɧɨɝɢɦɢ
ɢɫɫɥɟɞɨɜɚɬɟɥɹɦɢ, ɧɨ ɧɟɨɞɧɨɡɧɚɱɧɨɫɬɶ ɝɟɧɟɬɢɱɟɫɤɢɯ ɢɧɬɟɪɩɪɟɬɚɰɢɣ ɨɛɭɫɥɨɜɢɥɚ
ɧɟɨɛɯɨɞɢɦɨɫɬɶ
ɩɪɨɜɟɞɟɧɢɹ
ɞɨɩɨɥɧɢɬɟɥɶɧɵɯ
ɤɨɦɩɥɟɤɫɧɵɯ
ɦɢɧɟɪɚɥɨɝɢɱɟɫɤɢɯ,
ɝɟɨɯɢɦɢɱɟɫɤɢɯ ɢ ɬɟɪɦɨɛɚɪɨɝɟɨɯɢɦɢɱɟɫɤɢɯ ɢɫɫɥɟɞɨɜɚɧɢɣ.
ɋɬɪɟɥɶɰɨɜɫɤɚɹ ɤɚɥɶɞɟɪɚ ɜɵɩɨɥɧɟɧɚ ɜɭɥɤɚɧɨɝɟɧɧɨ-ɨɫɚɞɨɱɧɵɦɢ ɩɨɪɨɞɚɦɢ ɩɨɡɞɧɟɝɨ
ɦɟɡɨɡɨɹ. Ɏɭɧɞɚɦɟɧɬ ɤɚɥɶɞɟɪɵ ɫɥɨɠɟɧ ɚɪɯɟɣɫɤɨ-ɩɚɥɟɨɡɨɣɫɤɢɦɢ ɦɟɬɚɦɨɪɮɢɱɟɫɤɢɦɢ ɩɨɪɨɞ
ɢ ɝɪɚɧɢɬɨɢɞɚɦɢ. Ɇɟɫɬɨɪɨɠɞɟɧɢɟ Ⱥɧɬɟɣ ɪɚɫɩɨɥɨɠɟɧɨ ɜ ɝɪɚɧɢɬɚɯ ɮɭɧɞɚɦɟɧɬɚ ɢ
ɤɨɧɬɪɨɥɢɪɭɟɬɫɹ ɤɪɭɬɨɩɚɞɚɸɳɢɦ ɫɭɛɦɟɪɢɞɢɨɧɚɥɶɧɵɦ ɲɜɨɦ ʋ160. ɋɬɪɟɥɶɰɨɜɫɤɨɟ
ɦɟɫɬɨɪɨɠɞɟɧɢɟ ɥɨɤɚɥɢɡɨɜɚɧɨ ɜɵɲɟ ɦɟɫɬɨɪɨɠɞɟɧɢɹ Ⱥɧɬɟɣ ɜ ɜɭɥɤɚɧɨɝɟɧɧɵɯ ɩɨɪɨɞɚɯ
ɤɚɥɶɞɟɪɵ, ɪɭɞɧɵɟ ɬɟɥɚ ɤɨɧɬɪɨɥɢɪɭɸɬɫɹ ɩɪɟɢɦɭɳɟɫɬɜɟɧɧɨ ɫɟɜɟɪɨ-ɡɚɩɚɞɧɵɦɢ ɪɚɡɥɨɦɚɦɢ.
Ɉɫɧɨɜɧɵɟ ɱɟɪɬɵ ɦɢɧɟɪɚɥɢɡɚɰɢɢ ɭɪɚɧɨɜɨɪɭɞɧɨɝɨ ɷɬɚɩɚ ɧɚ ɷɬɢɯ ɦɟɫɬɨɪɨɠɞɟɧɢɹɯ ɛɥɢɡɤɢ.
ȼ ɪɚɧɧɟɦɟɥɨɜɨɦ ɝɢɞɪɨɬɟɪɦɚɥɶɧɨɦ ɷɬɚɩɟ ɜɵɞɟɥɟɧɵ ɱɟɬɵɪɟ ɫɬɚɞɢɢ: ɞɨɪɭɞɧɚɹ,
ɭɪɚɧɨɜɨɪɭɞɧɚɹ, ɩɟɪɜɚɹ ɢ ɜɬɨɪɚɹ ɩɨɫɬɪɭɞɧɵɟ. ȼ ɬɟɱɟɧɢɟ ɞɨɪɭɞɧɨɣ ɫɬɚɞɢɢ ɩɪɨɢɫɯɨɞɢɥɨ
ɦɟɬɚɫɨɦɚɬɢɱɟɫɤɨɟ ɩɪɟɨɛɪɚɡɨɜɚɧɢɟ ɜɦɟɳɚɸɳɢɯ ɩɨɪɨɞ, ɨɛɪɚɡɨɜɚɥɢɫɶ ɛɪɟɤɱɢɢ ɫ
ɤɪɢɩɬɨɤɜɚɪɰɟɜɵɦ ɰɟɦɟɧɬɨɦ, ɫɭɥɶɮɢɞɧɨ-ɤɚɪɛɨɧɚɬɧɨ - ɤɜɚɪɰɟɜɵɟ ɠɢɥɵ ɢ ɩɪɨɠɢɥɤɢ ɫ
ɚɥɶɛɢɬɨɦ, ɧɚ ɡɚɜɟɪɲɚɸɳɢɯ ɫɬɭɩɟɧɹɯ - ɡɟɪɧɢɫɬɵɣ ɤɜɚɪɰ ɜɦɟɫɬɟ ɫ ɢɥɥɢɬɨɦ.
ȼ ɭɪɚɧɨɜɨɪɭɞɧɭɸ ɫɬɚɞɢɸ ɫɮɨɪɦɢɪɨɜɚɥɢɫɶ ɛɪɚɧɧɟɪɢɬ-ɧɚɫɬɭɪɚɧɨɜɵɟ ɪɭɞɵ ɫ ɤɜɚɪɰɟɦ
ɢ ɮɥɸɨɪɢɬɨɦ, ɡɨɧɵ ɪɭɞɨɫɨɩɪɨɜɨɠɞɚɸɳɟɣ ɚɥɶɛɢɬɢɡɚɰɢɢ ɢ ɝɟɦɚɬɢɬɢɡɚɰɢɢ. ȼɵɞɟɥɟɧɵ ɞɜɟ
ɝɟɧɟɪɚɰɢɢ ɤɜɚɪɰɚ. Ʉɜɚɪɰ 1 ɪɚɡɜɢɬ ɧɟɡɧɚɱɢɬɟɥɶɧɨ, ɨɧ ɯɚɪɚɤɬɟɪɢɡɭɟɬɫɹ ɬɨɧɤɨɡɟɪɧɢɫɬɨɣ
ɫɬɪɭɤɬɭɪɨɣ, ɢɦɩɪɟɝɧɢɪɨɜɚɧ ɬɨɧɤɨɞɢɫɩɟɪɫɧɵɦɢ ɨɤɢɫɥɚɦɢ ɠɟɥɟɡɚ ɢ, ɤɚɤ ɩɪɚɜɢɥɨ,
ɰɟɦɟɧɬɢɪɭɟɬ ɨɛɥɨɦɤɢ ɜɦɟɳɚɸɳɢɯ ɩɨɪɨɞ. Ʉɜɚɪɰ 2 ɪɚɫɩɪɨɫɬɪɚɧɟɧ ɛɨɥɟɟ ɲɢɪɨɤɨ, ɨɫɨɛɟɧɧɨ
ɧɚ ɦɟɫɬɨɪɨɠɞɟɧɢɢ Ⱥɧɬɟɣ. Ɉɧ ɛɨɥɟɟ ɤɪɭɩɧɨɡɟɪɧɢɫɬɵɣ (ɞɨ ɩɟɪɜɵɯ ɦɦ),
ɤɨɪɨɬɤɨɩɪɢɡɦɚɬɢɱɟɫɤɢɣ ɛɢɩɢɪɚɦɢɞɚɥɶɧɵɣ, ɱɢɫɬ ɨɬ ɬɜɟɪɞɵɯ ɜɤɥɸɱɟɧɢɣ. Ɉɫɧɨɜɧɚɹ ɦɚɫɫɚ
ɤɜɚɪɰɚ ɷɬɨɣ ɝɟɧɟɪɚɰɢɢ ɨɛɪɚɡɨɜɚɥɚɫɶ ɞɨ ɧɚɫɬɭɪɚɧɚ, ɬɨɝɞɚ ɤɚɤ ɩɨɫɥɟɞɧɢɟ ɡɨɧɵ ɪɨɫɬɚ
64
ɮɨɪɦɢɪɨɜɚɥɢɫɶ ɫɨɜɦɟɫɬɧɨ ɫ ɩɟɪɜɵɦɢ ɡɚɪɨɠɞɟɧɢɹɦɢ ɦɟɥɤɨɫɮɟɪɨɥɢɬɨɜɨɝɨ ɧɚɫɬɭɪɚɧɚ.
ɉɟɪɜɢɱɧɵɟ ɛɪɚɧɧɟɪɢɬ-ɧɚɫɬɭɪɚɧɨɜɵɟ ɪɭɞɵ ɨɬɥɚɝɚɥɢɫɶ ɜ ɩɚɪɚɝɟɧɟɡɢɫɟ ɫ ɮɥɸɨɪɢɬɨɦ.
ȼ ɩɨɫɬɪɭɞɧɭɸ ɫɬɚɞɢɸ ɩɟɪɜɢɱɧɵɟ ɪɭɞɵ ɛɵɥɢ ɢɧɬɟɧɫɢɜɧɨ ɡɚɦɟɳɟɧɵ U-Si-ɦɟɬɚɝɟɥɟɦ,
ɤɨɬɨɪɵɣ ɪɚɧɟɟ ɫɱɢɬɚɥɫɹ ɤɨɮɮɢɧɢɬɨɦ. Ʉɜɚɪɰ ɩɨɫɬɪɭɞɧɨɣ ɫɬɚɞɢɢ ɪɚɫɩɪɨɫɬɪɚɧɟɧ ɜ ɪɭɞɧɨɦ
ɩɨɥɟ ɧɚɢɛɨɥɟɟ ɲɢɪɨɤɨ. Ɉɧ ɨɛɪɚɡɨɜɚɥɫɹ ɜ ɧɚɱɚɥɟ ɩɨɫɬɪɭɞɧɨɣ ɫɬɚɞɢɢ ɜ ɜɢɞɟ ɝɪɟɛɟɧɱɚɬɵɯ
ɤɪɢɫɬɚɥɥɨɜ ɪɚɡɦɟɪɨɦ ɨɬ ɞɨɥɟɣ ɦɢɥɥɢɦɟɬɪɚ ɞɨ 1 ɫɦ. ɇɚɪɹɞɭ ɫ ɠɢɥɶɧɵɦ ɜɵɩɨɥɧɟɧɢɟɦ ɨɧ
ɦɟɬɚɫɨɦɚɬɢɱɟɫɤɢ ɪɚɡɜɢɜɚɥɫɹ ɢ ɜɨ ɜɦɟɳɚɸɳɢɯ ɩɨɪɨɞɚɯ.
Ɇɟɬɨɞɵ ɢɫɫɥɟɞɨɜɚɧɢɹ. ɉɟɪɜɢɱɧɵɟ ɢɧɞɢɜɢɞɭɚɥɶɧɵɟ ɮɥɸɢɞɧɵɟ ɜɤɥɸɱɟɧɢɹ (Ɏȼ) ɜ
ɤɜɚɪɰɟ ɭɪɚɧɨɜɨɪɭɞɧɨɣ ɢ ɩɨɫɬɪɭɞɧɨɣ ɫɬɚɞɢɣ ɢɡɭɱɟɧɵ ɦɟɬɨɞɚɦɢ ɦɢɤɪɨɬɟɪɦɨɦɟɬɪɢɢ ɢ
Ɋɚɦɚɧɨɜɫɤɨɣ ɫɩɟɤɬɪɨɫɤɨɩɢɢ. Ɇɟɬɨɞɚɦɢ ɦɢɤɪɨɬɟɪɦɨɦɟɬɪɢɢ ɧɚ ɬɟɪɦɨɤɪɢɨɤɚɦɟɪɟ LinkamTHMSG-600 ɜ ɂȽȿɆ ɊȺɇ ɨɩɪɟɞɟɥɟɧɵ ɬɟɦɩɟɪɚɬɭɪɵ ɝɨɦɨɝɟɧɢɡɚɰɢɢ (Ɍɝɨɦ), ɬɟɦɩɟɪɚɬɭɪɵ
ɩɥɚɜɥɟɧɢɹ ɷɜɬɟɤɬɢɤɢ (Ɍɷɜɬ) ɢ ɬɟɦɩɟɪɚɬɭɪɵ ɩɥɚɜɥɟɧɢɹ ɥɶɞɚ. ɉɪɢ ɢɧɬɟɪɩɪɟɬɚɰɢɢ
ɪɟɡɭɥɶɬɚɬɨɜ Ɍɝɨɦ ɫɱɢɬɚɥɢɫɶ ɦɢɧɢɦɚɥɶɧɵɦɢ ɬɟɦɩɟɪɚɬɭɪɚɦɢ ɮɥɸɢɞɨɜ. Ʉɚɤ ɜɢɞɧɨ ɢɡ
ɩɪɢɜɟɞɟɧɧɵɯ ɧɢɠɟ ɪɢɫɭɧɤɨɜ, ɜɫɟ ɢɡɦɟɪɟɧɧɵɟ Ɍɷɜɬ ɢɦɟɸɬ ɡɧɚɱɟɧɢɹ ɜɵɲɟ -33ɨɋ,
ɫɥɟɞɨɜɚɬɟɥɶɧɨ ɨɫɧɨɜɧɵɦ ɤɚɬɢɨɧɨɦ ɜ ɪɚɫɬɜɨɪɚɯ Ɏȼ ɹɜɥɹɟɬɫɹ Na+. ȼ ɬɨ ɠɟ ɜɪɟɦɹ ɦɧɨɝɢɟ
Ɏȼ ɢɦɟɸɬ Ɍɷɜɬ ɫɭɳɟɫɬɜɟɧɧɨ ɧɢɠɟ ɬɟɨɪɟɬɢɱɟɫɤɢɯ ɡɧɚɱɟɧɢɣ ɞɥɹ ɫɢɫɬɟɦ ɫ ɷɜɬɟɤɬɢɤɚɦɢ ɜ
ɷɬɨɣ ɨɛɥɚɫɬɢ, ɱɬɨ ɭɤɚɡɵɜɚɟɬ ɧɚ ɩɪɢɫɭɬɫɬɜɢɟ ɜ ɪɚɫɬɜɨɪɚɯ ɧɟɤɨɬɨɪɨɝɨ ɤɨɥɢɱɟɫɬɜɚ ɞɪɭɝɢɯ
ɤɚɬɢɨɧɨɜ. Ɇɟɬɨɞɨɦ Ɋɚɦɚɧɨɜɫɤɨɣ ɫɩɟɤɬɪɨɫɤɨɩɢɢ (Ɋɋ) ɜ ɥɚɛɨɪɚɬɨɪɢɢ G2R CREGU
ɍɧɢɜɟɪɫɢɬɟɬɚ ɢɦ. Ⱥ. ɉɭɚɧɤɚɪɟ ɜ ɝ. ɇɚɧɫɢ (Ɏɪɚɧɰɢɹ) ɚɧɚɥɢɡɢɪɨɜɚɥɫɹ ɫɨɫɬɚɜ ɝɚɡɨɜɨɣ ɮɚɡɵ
ɢ ɫɨɞɟɪɠɚɧɢɟ ɢɨɧɚ ɇɋɈ3- ɜ ɪɚɫɬɜɨɪɚɯ Ɏȼ. Ʉɨɧɰɟɧɬɪɚɰɢɹ ɮɥɸɢɞɨɜ ɪɚɫɫɱɢɬɵɜɚɥɢɫɶ ɩɨ
ɬɟɦɩɟɪɚɬɭɪɟ ɩɥɚɜɥɟɧɢɹ ɥɶɞɚ ɫ ɩɨɦɨɳɶɸ ɩɪɨɝɪɚɦɦɵ FLINCOR (Brown, 1990) ɢ ɜ ɬɟɤɫɬɟ
ɩɪɢɜɨɞɹɬɫɹ ɜ ɦɚɫ. %, ɷɤɜ. NaCl.
ɍɪɚɧɨɜɨɪɭɞɧɚɹ ɫɬɚɞɢɹ. Ɋɟɡɭɥɶɬɚɬɵ ɢɫɫɥɟɞɨɜɚɧɢɹ Ɏȼ ɩɪɢɜɟɞɟɧɵ ɧɚ ɪɢɫ. 1.
Ɏɥɸɢɞɧɵɟ ɜɤɥɸɱɟɧɢɹ ɜ ɤɜɚɪɰɟ 1, ɰɟɦɟɧɬɢɪɭɸɳɟɦ ɨɛɥɨɦɤɢ ɜɦɟɳɚɸɳɢɯ ɩɨɪɨɞ,
ɯɚɪɚɤɬɟɪɢɡɭɸɬ ɧɚɱɚɥɨ ɭɪɚɧɨɜɨ-ɪɭɞɧɨɝɨ ɩɪɨɰɟɫɫɚ. Ⱦɨɫɬɭɩɧɵɟ ɞɥɹ ɢɡɭɱɟɧɢɹ ɨɞɢɧɨɱɧɵɟ Ɏȼ
(>5-7 ɦɤɦ) ɛɵɥɢ ɨɛɧɚɪɭɠɟɧɵ ɬɨɥɶɤɨ ɧɚ ɦɟɫɬɨɪɨɠɞɟɧɢɢ ɋɬɪɟɥɶɰɨɜɫɤɨɟ. Ɉɧɢ ɢɦɟɸɬ
ɞɜɭɯɮɚɡɧɵɣ ɫɨɫɬɚɜ, ɝɚɡ ɡɚɧɢɦɚɟɬ ɞɨ 50-60% ɨɛɴɟɦɚ. ɉɪɨɰɟɫɫ ɪɭɞɨɨɛɪɚɡɨɜɚɧɢɹ ɧɚɱɢɧɚɥɫɹ
ɩɪɢ ɬɟɦɩɟɪɚɬɭɪɚɯ 530-500ɨɋ (ɤɜɚɪɰ 1, ɪɢɫ. 1). Ɏɥɸɢɞɵ ɢɦɟɥɢ Na-(ɇɋɈ3)-ɋl ɫɨɫɬɚɜ. ɉɪɢ
ɤɪɢɨɦɟɬɪɢɢ ɨɩɪɟɞɟɥɢɬɶ ɫɨɫɬɚɜ ɩɨɫɥɟɞɧɟɣ ɪɚɫɩɥɚɜɢɜɲɟɣɫɹ ɮɚɡɵ ɧɟ ɭɞɚɥɨɫɶ, ɩɨ-ɜɢɞɢɦɨɦɭ,
ɷɬɨ ɛɵɥɢ ɝɢɞɪɚɬɵ ɫɨɥɟɣ. ȼ ɷɬɨɦ ɫɥɭɱɚɟ ɤɨɧɰɟɧɬɪɚɰɢɹ ɮɥɸɢɞɨɜ cɨɫɬɚɜɥɹɟɬ 23.2-26 ɦɚɫ. %.
ȼɤɥɸɱɟɧɢɹ ɜ ɤɜɚɪɰɟ 2 ɯɚɪɚɤɬɟɪɢɡɭɸɬ ɧɚɱɚɥɨ ɨɬɥɨɠɟɧɢɹ ɩɟɪɜɢɱɧɨɝɨ ɧɚɫɬɭɪɚɧɚ. ɇɚ
ɦɟɫɬɨɪɨɠɞɟɧɢɢ ɋɬɪɟɥɶɰɨɜɫɤɨɟ ɜɫɟ ɢɡɭɱɟɧɧɵɟ Ɏȼ ɢɦɟɸɬ ɞɜɭɯɮɚɡɧɵɣ ɫɨɫɬɚɜ,
ɫɨɨɬɧɨɲɟɧɢɟ ɮɚɡ ɜ ɝɪɭɩɩɚɯ Ɏȼ ɩɨɫɬɨɹɧɧɨ, ɩɪɢɡɧɚɤɢ ɜɫɤɢɩɚɧɢɹ ɮɥɸɢɞɨɜ ɧɟ ɧɚɛɥɸɞɚɥɢɫɶ.
Ʉɪɢɫɬɚɥɥɢɡɚɰɢɹ ɤɜɚɪɰɚ ɩɪɨɢɫɯɨɞɢɥɚ ɜ ɢɧɬɟɪɜɚɥɟ 415-280ɨɋ. ȼ ɧɟɤɨɬɨɪɵɯ Ɏȼ ɩɪɢ
ɬɟɦɩɟɪɚɬɭɪɚɯ ɨɤɨɥɨ 400ɨɋ ɝɨɦɨɝɟɧɢɡɚɰɢɹ ɩɪɨɢɫɯɨɞɢɥɚ ɩɪɢ ɢɫɱɟɡɧɨɜɟɧɢɢ ɦɟɧɢɫɤɚ, ɱɬɨ
ɧɚɪɹɞɭ ɫ ɪɚɫɱɟɬɚɦɢ ɭɤɚɡɵɜɚɟɬ ɧɚ ɨɤɨɥɨɤɪɢɬɢɱɟɫɤɨɟ ɫɨɫɬɨɹɧɢɟ ɮɥɸɢɞɚ. ɇɚ Ⱥɧɬɟɟ
ɧɟɤɨɬɨɪɵɟ ɝɪɭɩɩɵ Ɏȼ ɫɨɞɟɪɠɚɬ ɬɜɟɪɞɭɸ ɮɚɡɭ. ɉɪɢɡɧɚɤɢ ɜɫɤɢɩɚɧɢɹ ɮɥɸɢɞɨɜ ɬɚɤ ɠɟ, ɤɚɤ
ɢ ɧɚ ɋɬɪɟɥɶɰɨɜɫɤɨɦ ɦɟɫɬɨɪɨɠɞɟɧɢɢ, ɧɟ ɨɛɧɚɪɭɠɟɧɵ. ȼɟɪɯɧɢɣ ɩɪɟɞɟɥ ɬɟɦɩɟɪɚɬɭɪɵ
ɮɥɸɢɞɨɜ ɧɚ Ⱥɧɬɟɟ ɛɵɥ ɧɟɫɤɨɥɶɤɨ ɜɵɲɟ, ɨɛɳɢɣ ɢɧɬɟɪɜɚɥ ɫɨɫɬɚɜɥɹɟɬ 460-280ɨɋ.
Ɉɬɥɨɠɟɧɢɟ ɛɪɚɧɧɟɪɢɬɚ ɢ ɧɚɫɬɭɪɚɧɚ ɩɪɨɢɫɯɨɞɢɥɨ ɩɨɫɥɟ ɨɬɥɨɠɟɧɢɹ ɨɫɧɨɜɧɨɣ ɦɚɫɫɵ
ɤɜɚɪɰɚ 2, ɩɪɢ ɤɪɢɫɬɚɥɥɢɡɚɰɢɢ ɧɚɢɛɨɥɟɟ ɩɨɡɞɧɢɯ ɡɨɧ ɤɜɚɪɰɟɜɵɯ ɤɪɢɫɬɚɥɥɨɜ, ɩɪɢ
ɩɨɧɢɠɟɧɢɢ ɬɟɦɩɟɪɚɬɭɪɵ ɞɨ 350-300ɨɋ.
Ɇɢɧɟɪɚɥɨɨɛɪɚɡɭɸɳɢɟ ɮɥɸɢɞɵ ɧɚ ɦɟɫɬɨɪɨɠɞɟɧɢɢ ɋɬɪɟɥɶɰɨɜɫɤɨɟ ɢɦɟɥɢ ɜ ɨɫɧɨɜɧɨɦ
Na-ɋl ɫɨɫɬɚɜ. ɇɚ Ⱥɧɬɟɟ ɦɢɧɟɪɚɥɨɨɛɪɚɡɨɜɚɧɢɟ ɩɪɨɢɫɯɨɞɢɥɨ ɢɡ Na-ɇɋɈ3-ɋl ɮɥɸɢɞɨɜ,
ɢɧɨɝɞɚ ɫɨɞɟɪɠɚɳɢɯ CO32- - ɢɨɧ, ɱɬɨ ɭɤɚɡɵɜɚɟɬ ɧɚ ɫɥɚɛɨɳɟɥɨɱɧɨɣ ɢɥɢ ɳɟɥɨɱɧɨɣ ɯɚɪɚɤɬɟɪ
ɫɪɟɞɵ. Ɍɜɟɪɞɚɹ ɮɚɡɚ ɜɨ ɜɤɥɸɱɟɧɢɢ ɫ Ɍɝɨɦ = 370ɨɋ ɹɜɥɹɟɬɫɹ ɧɚɯɤɨɥɢɬɨɦ. Ɋɭɞɨɨɛɪɚɡɭɸɳɢɟ
ɮɥɸɢɞɵ ɧɚ Ⱥɧɬɟɟ ɨɬɥɢɱɚɸɬɫɹ ɨɬ ɮɥɸɢɞɨɜ ɋɬɪɟɥɶɰɨɜɫɤɨɝɨ ɦɟɫɬɨɪɨɠɞɟɧɢɹ ɧɟ ɬɨɥɶɤɨ
ɛɨɥɟɟ ɜɵɫɨɤɢɦɢ ɬɟɦɩɟɪɚɬɭɪɚɦɢ ɢ ɛɨɥɟɟ ɜɵɫɨɤɨɣ ɳɟɥɨɱɧɨɫɬɶɸ, ɧɨ ɢ ɛɨɥɟɟ ɜɵɫɨɤɨɣ
ɫɨɥɟɧɨɫɬɶɸ. Ʉɨɧɰɟɧɬɪɚɰɢɹ ɮɥɸɢɞɨɜ ɧɚ ɋɬɪɟɥɶɰɨɜɫɤɨɦ ɫɨɫɬɚɜɥɹɥɚ 7-1 ɦɚɫ. %, ɧɚ Ⱥɧɬɟɟ
ɛɵɥɚ ɡɧɚɱɢɬɟɥɶɧɨ ɜɵɲɟ (ɨɫɨɛɟɧɧɨ ɜɟɪɯɧɢɣ ɩɪɟɞɟɥ) ɢ ɜɚɪɶɢɪɨɜɚɥɚ ɨɬ 26 ɞɨ 0.5 ɦɚɫ. %.
65
Ƚɚɡɨɜɚɹ ɮɚɡɚ ɮɥɸɢɞɨɜ
ɭɪɚɧɨɜɨ-ɪɭɞɧɨɣ
600
Quartz I
Quartz I
ɫɬɚɞɢɢ ɢɦɟɥɚ ɜɨɞɧɵɣ
550
550
ɫɨɫɬɚɜ.
Ɋɚɦɚɧɨɜɫɤɢɦɢ
500
500
ɚɧɚɥɢɡɚɦɢ ɨɛɧɚɪɭɠɟɧɵ
450
ɬɨɥɶɤɨ ɦɨɥɟɤɭɥɹɪɧɵɟ Ɉ2
450
(ɨɬ
100 ɞɨ 88 ɦɨɥ.%) ɢ
400
400
ɇ2, ɤɨɬɨɪɵɟ ɹɜɥɹɸɬɫɹ
350
350
ɩɪɨɞɭɤɬɚɦɢ ɪɚɞɢɨɥɢɡɚ
300
300
ɜɨɞɵ
ɢ/ɢɥɢ
ɨɪɝɚɧɢ250
ɱɟɫɤɨɝɨ ɜɟɳɟɫɬɜɚ. ȼ ɞɜɭɯ
250
Ɏȼ ɧɚ ɦɟɫɬɨɪɨɠɞɟɧɢɢ
200
200
-35 -30 -25 -20 -15 -10
-5
0
Ⱥɧɬɟɣ ɛɵɥɚ ɨɛɧɚɪɭɠɟɧɚ
0
5
10
15
20
25
30
T eut, oC
C,
wt.
%
ɋɈ2. Ɇɟɬɚɧ ɢ ɞɪɭɝɢɟ
Antei
S treltsovskoe
Antei S tretsovsky
ɝɚɡɵ ɧɟ ɨɛɧɚɪɭɠɟɧɵ.
Ʉ ɫɨɠɚɥɟɧɢɸ, ɧɟ
Ɋɢɫ. 1. Ɍɟɦɩɟɪɚɬɭɪɵ ɝɨɦɨɝɟɧɢɡɚɰɢɢ, ɬɟɦɩɟɪɚɬɭɪɵ ɩɥɚɜɥɟɧɢɹ ɫɭɳɟɫɬɜɭɟɬ
ɦɟɬɨɞɨɜ,
ɷɜɬɟɤɬɢɤɢ ɢ ɤɨɧɰɟɧɬɪɚɰɢɹ ɪɚɫɬɜɨɪɨɜ ɮɥɸɢɞɧɵɯ ɜɤɥɸɱɟɧɢɣ ɜ ɩɨɡɜɨɥɹɸɳɢɯ
ɞɨɫɬɨɤɜɚɪɰɟ ɭɪɚɧɨɜɨ-ɪɭɞɧɨɣ ɫɬɚɞɢɢ
ɜɟɪɧɨ ɨɩɪɟɞɟɥɹɬɶ F-ɢɨɧ ɜ
Fig. 1. The homogenization temperatures, the eutectic melting ɫɨɫɬɚɜɟ
Ɏȼ,
ɧɨ
temperatures and fluid salinity measured for fluid inclusions in quartz ɩɚɪɚɝɟɧɟɡɢɫ ɧɚɫɬɭɪɚɧɚ ɢ
and of uranium ore stage.
ɮɥɸɨɪɢɬɚ (Ⱥɥɟɲɢɧ ɢ
ɞɪ., 2007) ɫɜɢɞɟɬɟɥɶɫɬɜɭɟɬ ɨ ɬɨɦ, ɱɬɨ ɜ ɦɢɧɟɪɚɥɨɨɛɪɚɡɭɸɳɟɣ ɫɢɫɬɟɦɟ ɩɪɢɫɭɬɫɬɜɨɜɚɥɨ
ɡɧɚɱɢɬɟɥɶɧɨɟ ɤɨɥɢɱɟɫɬɜɨ ɮɬɨɪɚ.
ɉɨɫɬɪɭɞɧɚɹ ɫɬɚɞɢɹ. Ɋɟɡɭɥɶɬɚɬɵ ɢɫɫɥɟɞɨɜɚɧɢɹ Ɏȼ ɜ ɩɨɫɬɪɭɞɧɨɦ ɝɪɟɛɟɧɱɚɬɨɦ
ɤɜɚɪɰɟ ɯɚɪɚɤɬɟɪɢɡɭɸɳɢɟ ɭɫɥɨɜɢɹ ɩɟɪɟɨɬɥɨɠɟɧɢɹ ɩɟɪɜɢɱɧɵɯ ɪɭɞ, ɩɨɤɚɡɚɧɵ ɧɚ ɪɢɫ. 2.
ɂɡɭɱɟɧɵ ɨɛɪɚɡɰɵ ɢɡ ɪɚɡɥɢɱɧɵɯ ɩɨ ɦɚɫɲɬɚɛɚɦ ɢ ɫɬɪɭɤɬɭɪɧɨɦɭ ɩɨɥɨɠɟɧɢɸ ɪɭɞɧɵɯ ɡɨɧ.
ɉɨɞɚɜɥɹɸɳɟɟ ɛɨɥɶɲɢɧɫɬɜɨ Ɏȼ ɢɦɟɟɬ ɞɜɭɯɮɚɡɧɵɣ ɫɨɫɬɚɜ, ɫɨɨɬɧɨɲɟɧɢɟ ɮɚɡ ɜ ɝɪɭɩɩɚɯ Ɏȼ
ɩɨɫɬɨɹɧɧɨ, ɩɪɢɡɧɚɤɢ ɜɫɤɢɩɚɧɢɹ ɮɥɸɢɞɨɜ ɧɟ ɧɚɛɥɸɞɚɸɬɫɹ.
ɇɟɫɦɨɬɪɹ ɧɚ ɬɨ, ɱɬɨ Ⱥɧɬɟɣ ɢ ɋɬɪɟɥɶɰɨɜɫɤɨɟ ɥɨɤɚɥɢɡɨɜɚɧɵ ɧɚ ɪɚɡɥɢɱɧɨɣ ɝɥɭɛɢɧɟ ɢ ɜ
ɪɚɡɧɵɯ ɜɦɟɳɚɸɳɢɯ ɩɨɪɨɞɚɯ, ɬɟɦɩɟɪɚɬɭɪɵ ɢ ɫɨɫɬɚɜ ɮɥɸɢɞɨɜ ɩɪɢ ɩɟɪɟɨɬɥɨɠɟɧɢɢ
ɩɟɪɜɢɱɧɵɯ ɪɭɞ ɧɚ ɷɬɢɯ ɦɟɫɬɨɪɨɠɞɟɧɢɹɯ ɛɵɥɢ ɛɥɢɡɤɢ ɢ ɩɨɧɢɠɚɥɢɫɶ ɡɚɤɨɧɨɦɟɪɧɨ ɩɨ ɦɟɪɟ
ɭɞɚɥɟɧɢɹ ɨɬ Ƚɥɚɜɧɨɝɨ ɪɚɡɥɨɦɚ. ɇɚ ɋɬɪɟɥɶɰɨɜɫɤɨɦ ɜ ɪɚɡɥɨɦɟ ɬɟɦɩɟɪɚɬɭɪɵ ɫɨɫɬɚɜɥɹɥɢ 365200ɨɋ ɢ ɧɟ ɩɪɟɜɵɲɚɥɢ 250ɨɋ ɜ ɡɨɧɟ ɜɥɢɹɧɢɹ ɪɚɡɥɨɦɚ. ɇɚ Ⱥɧɬɟɟ ɪɭɞɨɨɛɪɚɡɨɜɚɧɢɟ ɜ
ɪɚɡɥɨɦɟ ɩɪɨɢɫɯɨɞɢɥɨ ɜ ɢɧɬɟɪɜɚɥɟ 390-180ɨɋ, ɧɚ ɦɚɤɫɢɦɚɥɶɧɨɦ ɭɞɚɥɟɧɢɢ ɨɬ ɪɚɡɥɨɦɚ – ɩɪɢ
ɬɟɦɩɟɪɚɬɭɪɚɯ 210-170ɨɋ. Ɉɱɟɧɶ ɜɵɫɨɤɢɟ ɬɟɦɩɟɪɚɬɭɪɵ ɜ Ƚɥɚɜɧɨɦ ɪɚɡɥɨɦɟ, ɩɨ-ɜɢɞɢɦɨɦɭ,
ɭɤɚɡɵɜɚɸɬ ɧɚ ɬɨ, ɱɬɨ ɦɟɠɞɭ ɨɬɥɨɠɟɧɢɟɦ ɢ ɩɟɪɟɨɬɥɨɠɟɧɢɟɦ ɪɭɞ ɧɟ ɛɵɥɨ ɡɧɚɱɢɬɟɥɶɧɨɝɨ
ɩɟɪɟɪɵɜɚ ɜɨ ɜɪɟɦɟɧɢ.
Ɏɥɸɢɞɵ ɢɦɟɥɢ Na-ɋl ɢɥɢ Na-HCO3-Cl ɫɨɫɬɚɜ, ɤɨɧɰɟɧɬɪɚɰɢɹ ɢɯ ɜɚɪɶɢɪɨɜɚɥɚ ɨɬ 1415 ɞɨ 1 ɦɚɫ. %, ɦɚɤɫɢɦɚɥɶɧɵɟ ɟɟ ɡɧɚɱɟɧɢɹ ɯɚɪɚɤɬɟɪɧɵ ɞɥɹ ɝɥɭɛɢɧɧɨɝɨ ɪɚɡɥɨɦɚ. Ƚɚɡɨɜɚɹ
ɮɚɡɚ ɫɨɞɟɪɠɚɥɚ ɋɈ2 ɢ ɦɨɥɟɤɭɥɹɪɧɵɟ Ɉ2 ɢ ɇ2 ɜ ɪɚɡɥɢɱɧɵɯ ɫɨɨɬɧɨɲɟɧɢɹɯ. Ʉɨɥɢɱɟɫɬɜɚ ɋɈ2
ɢ ɢɨɧɚ ɇɋɈ3- ɜɨɡɪɚɫɬɚɥɢ ɩɨ ɦɟɪɟ ɭɞɚɥɟɧɢɹ ɨɬ ɪɚɡɥɨɦɚ. ȼ ɟɞɢɧɢɱɧɵɯ Ɏȼ ɡɚ ɩɪɟɞɟɥɚɦɢ
Ƚɥɚɜɧɨɝɨ ɪɚɡɥɨɦɚ ɨɛɧɚɪɭɠɟɧ ɦɟɬɚɧ (>2.5 ɦɨɥ. %). Ɉɱɟɜɢɞɧɨ, ɱɬɨ ɬɚɤɨɟ ɡɚɤɨɧɨɦɟɪɧɨɟ
ɢɡɦɟɧɟɧɢɟ ɫɨɫɬɚɜɚ ɨɛɭɫɥɨɜɥɟɧɨ ɜɡɚɢɦɨɞɟɣɫɬɜɢɟɦ ɮɥɸɢɞɨɜ ɫ ɜɦɟɳɚɸɳɢɦɢ ɩɨɪɨɞɚɦɢ.
Ɏɨɪɦɢɪɨɜɚɧɢɟ ɛɨɝɚɬɵɯ ɪɭɞ, ɥɨɤɚɥɢɡɨɜɚɧɧɵɯ ɩɪɟɢɦɭɳɟɫɬɜɟɧɧɨ ɜ Ƚɥɚɜɧɨɦ ɪɚɡɥɨɦɟ,
ɩɪɨɢɫɯɨɞɢɥɨ ɩɪɢ ɦɚɤɫɢɦɚɥɶɧɵɯ ɬɟɦɩɟɪɚɬɭɪɚɯ ɢɡ ɫɭɳɟɫɬɜɟɧɧɨ ɜɨɞɧɵɯ Na-ɯɥɨɪɢɞɧɵɯ
ɮɥɸɢɞɨɜ.
Ɂɚɤɥɸɱɟɧɢɟ. ɂɡɭɱɟɧɢɟ ɮɥɸɢɞɧɵɯ ɜɤɥɸɱɟɧɢɣ ɩɨɡɜɨɥɢɥɨ ɭɫɬɚɧɨɜɢɬɶ ɨɫɧɨɜɧɵɟ
ɫɜɨɣɫɬɜɚ ɪɭɞɨɨɛɪɚɡɭɸɳɢɯ ɮɥɸɢɞɨɜ: ɚ - ɜɵɫɨɤɢɟ ɬɟɦɩɟɪɚɬɭɪɵ ɨɬɥɨɠɟɧɢɹ ɢ
ɩɟɪɟɨɬɥɨɠɟɧɢɹ ɭɪɚɧɨɜɨɣ ɦɢɧɟɪɚɥɢɡɚɰɢɢ; ɛ – ɩɪɟɢɦɭɳɟɫɬɜɟɧɧɨ ɜɨɞɧɨ-ɫɨɥɟɜɨɣ ɫɨɫɬɚɜ
ɮɥɸɢɞɨɜ ɜ ɡɨɧɚɯ ɨɫɧɨɜɧɨɝɨ ɪɭɞɨɨɛɪɚɡɨɜɚɧɢɹ (ɪɨɥɶ ɩɪɨɞɭɤɬɨɜ ɪɚɞɢɨɥɢɡɚ ɜ
ɪɭɞɨɨɛɪɚɡɭɸɳɟɦ ɩɪɨɰɟɫɫɟ ɜ ɧɚɫɬɨɹɳɟɟ ɜɪɟɦɹ ɧɟɹɫɧɚ); ɜ - ɨɬɫɭɬɫɬɜɢɟ ɩɪɢɡɧɚɤɨɜ
ɜɫɤɢɩɚɧɢɹ ɮɥɸɢɞɨɜ. ȼ ɩɪɟɞɟɥɚɯ ɪɭɞɨɨɛɪɚɡɭɸɳɟɣ ɫɢɫɬɟɦɵ ɢɦɟɸɬɫɹ ɩɪɢɡɧɚɤɢ
Th, oC
600
66
Th, oC
ɬɟɦɩɟɪɚɬɭɪɧɨɣ
ɡɨɧɚɥɶɧɨɫɬɢ:
ɚ
ɧɚ
400
400
ɦɟɫɬɨɪɨɠɞɟɧɢɢ
Ⱥɧɬɟɣ
ɨɬɥɨɠɟɧɢɟ
ɢ
ɩɟɪɟ350
350
ɨɬɥɨɠɟɧɢɟ
ɪɭɞ
ɩɪɨɢɫɯɨ300
300
ɞɢɥɨ ɩɪɢ ɛɨɥɟɟ ɜɵɫɨɤɢɯ
250
250
ɬɟɦɩɟɪɚɬɭɪɚɯ, ɢɡ ɛɨɥɟɟ
ɫɨɥɟɧɵɯ ɢ ɛɨɥɟɟ ɳɟɥɨɱɧɵɯ
200
200
ɮɥɸɢɞɨɜ ɩɨ ɫɪɚɜɧɟɧɢɸ ɫɨ
150
150
ɋɬɪɟɥɶɰɨɜɫɤɢɦ
ɦɟɫɬɨ100
100
ɪɨɠɞɟɧɢɟɦ;
ɛ
–
ɬɟɦɩɟ0
5
10
15
20
0
5
10
15
C, wt %
ɪɚɬɭɪɵ ɢ ɫɨɫɬɚɜ ɮɥɸɢɞɨɜ
C,
wt
%
fault, high grade ore
fault, hidh grade ore
fault, ordinary ore
stockwork, ordinary ore
ɩɪɢ ɩɟɪɟɨɬɥɨɠɟɧɢɢ ɪɭɞ
stockwork, non commtrcial ore
stockwork, poor ore
zone of fault influence, poor ore
zone of fault influence, non commercial ore
ɡɚɤɨɧɨɦɟɪɧɨ ɦɟɧɹɸɬɫɹ ɩɨ
ɦɟɪɟ
ɭɞɚɥɟɧɢɹ
ɨɬ
Ɋɢɫ. 2. Ɍɟɦɩɟɪɚɬɭɪɵ ɝɨɦɨɝɟɧɢɡɚɰɢɢ ɢ ɤɨɧɰɟɧɬɪɚɰɢɢ ɨɫɧɨɜɧɨɝɨ
ɪɭɞɨɤɨɧɬɪɨɪɚɫɬɜɨɪɨɜ ɮɥɸɢɞɧɵɯ ɜɤɥɸɱɟɧɢɣ ɜ ɤɜɚɪɰɟ ɩɨɫɬɪɭɞɧɨɣ ɫɬɚɞɢɢ ɥɢɪɭɸɳɟɝɨ ɪɚɡɥɨɦɚ.
ɧɚ ɦɟɫɬɨɪɨɠɞɟɧɢɹɯ Ⱥɧɬɟɣ (Ⱥ) ɢ ɋɬɪɟɥɶɰɨɜɫɤɨɟ (Ȼ).
Ɇɢɧɟɪɚɥɨɝɨ-ɝɟɨɯɢɦɢFig. 2. The homogenization temperatures and fluid salinity
ɱɟɫɤɢɦɢ ɢɫɫɥɟɞɨɜɚɧɢɹɦɢ
measured for fluid inclusions in quartz of the post-ore stage in the
(Ⱥɥɟɲɢɧ ɢ ɞɪ., 2007)
Antei deposit (A) and in the Streltsovsky deposit (B).
ɭɫɬɚɧɨɜɥɟɧɨ ɫɥɟɞɭɸɳɟɟ: 1
− ɜ ɫɨɫɬɚɜɟ ɩɟɪɜɢɱɧɵɯ ɪɭɞ ɩɪɢɫɭɬɫɬɜɭɟɬ ɛɪɚɧɧɟɪɢɬ, ɬɟɦɩɟɪɚɬɭɪɵ ɨɛɪɚɡɨɜɚɧɢɹ ɤɨɬɨɪɨɝɨ
ɞɨɫɬɢɝɚɸɬ 300ɨɋ ɢ ɜɵɲɟ; 2 – ɜ ɫɨɫɬɚɜɟ ɜɦɟɳɚɸɳɢɯ ɩɨɪɨɞ ɬɚɤ ɠɟ, ɤɚɤ ɢ ɜ ɫɨɫɬɚɜɟ ɮɥɸɢɞɨɜ
ɩɪɚɤɬɢɱɟɫɤɢ ɨɬɫɭɬɫɬɜɭɟɬ ɨɪɝɚɧɢɤɚ ɢɥɢ ɞɪɭɝɢɟ ɜɨɫɫɬɚɧɨɜɢɬɟɥɢ U+6; 3 – ɫɭɳɟɫɬɜɭɟɬ
ɦɢɧɟɪɚɥɶɧɵɣ ɩɚɪɚɝɟɧɟɡɢɫ ɧɚɫɬɭɪɚɧɚ ɢ ɮɥɸɨɪɢɬɚ; 4 – ɭɫɬɚɧɨɜɥɟɧɵ Sm-Nd ɪɚɡɪɵɜ ɜ
ɧɨɪɦɢɪɨɜɚɧɧɵɯ ɤɪɢɜɵɯ ɢ ɫɬɚɬɢɫɬɢɱɟɫɤɢ ɡɧɚɱɢɦɵɣ ɬɟɬɪɚɞɧɵɣ ɷɮɮɟɤɬ W-ɬɢɩɚ ɜ
ɪɚɫɩɪɟɞɟɥɟɧɢɢ ɪɟɞɤɨɡɟɦɟɥɶɧɵɯ ɷɥɟɦɟɧɬɨɜ ɜ ɧɚɫɬɭɪɚɧɟ, ɯɚɪɚɤɬɟɪɧɵɟ ɬɨɥɶɤɨ ɞɥɹ ɤɢɫɥɵɯ
ɷɜɨɥɸɰɢɨɧɢɪɭɸɳɢɯ Li-F ɪɚɫɩɥɚɜɨɜ.
Ɉɱɟɜɢɞɧɨ, ɱɬɨ ɞɥɹ ɪɟɤɨɧɫɬɪɭɤɰɢɢ ɩɪɨɰɟɫɫɚ ɪɭɞɨɨɛɪɚɡɨɜɚɧɢɹ ɧɚ ɢɡɭɱɟɧɧɵɯ
ɦɟɫɬɨɪɨɠɞɟɧɢɹɯ ɧɟ ɦɨɠɟɬ ɛɵɬɶ ɢɫɩɨɥɶɡɨɜɚɧɚ ɨɛɳɟɩɪɢɧɹɬɚɹ ɦɨɞɟɥɶ (ɇɚɭɦɨɜ Ƚ.Ȼ., 1978),
ɫɨɝɥɚɫɧɨ ɤɨɬɨɪɨɣ ɨɬɥɨɠɟɧɢɟ ɭɪɚɧɨɜɵɯ ɪɭɞ ɩɪɨɢɫɯɨɞɢɥɨ ɩɪɢ ɬɟɦɩɟɪɚɬɭɪɚɯ 100-200ɨɋ,
ɭɪɚɧ ɩɟɪɟɧɨɫɢɥɫɹ ɩɨɪɨɜɵɦɢ ɪɚɫɬɜɨɪɚɦɢ ɜ ɜɢɞɟ ɭɪɚɧɢɥ-ɤɚɪɛɨɧɚɬɧɵɯ ɤɨɦɩɥɟɤɫɨɜ U6+,
ɤɨɬɨɪɵɟ ɪɚɡɪɭɲɚɥɢɫɶ ɜɫɥɟɞɫɬɜɢɟ ɭɞɚɥɟɧɢɹ ɋɈ2 ɩɪɢ ɜɫɤɢɩɚɧɢɢ ɮɥɸɢɞɨɜ, ɩɨɫɬɭɩɚɸɳɢɯ ɜ
ɨɬɤɪɵɬɵɟ ɩɨɥɨɫɬɢ ɪɚɡɥɨɦɨɜ. ȼɫɟ ɩɨɥɭɱɟɧɧɵɟ ɞɚɧɧɵɟ ɭɤɚɡɵɜɚɸɬ ɧɚ ɬɨ, ɱɬɨ
ɪɭɞɨɨɛɪɚɡɭɸɳɢɟ ɮɥɸɢɞɵ ɩɪɢ ɮɨɪɦɢɪɨɜɚɧɢɢ ɦɟɫɬɨɪɨɠɞɟɧɢɣ ɋɬɪɟɥɶɰɨɜɫɤɨɟ ɢ Ⱥɧɬɟɣ
ɢɦɟɥɢ ɦɚɝɦɚɬɢɱɟɫɤɭɸ ɩɪɢɪɨɞɭ. Ɇɨɠɧɨ ɩɨɥɚɝɚɬɶ, ɱɬɨ ɩɟɪɟɧɨɫ ɭɪɚɧɚ ɨɫɭɳɟɫɬɜɥɹɥɫɹ ɜ ɜɢɞɟ
ɮɬɨɪɢɞɧɵɯ (ɢɥɢ ɯɥɨɪɢɞɧɵɯ) ɤɨɦɩɥɟɤɫɨɜ U4+. Ƚɥɚɜɧɵɦ ɮɚɤɬɨɪɨɦ ɪɭɞɨɨɬɥɨɠɟɧɢɹ ɫɥɟɞɭɟɬ
ɫɱɢɬɚɬɶ ɩɨɧɢɠɟɧɢɟ ɬɟɦɩɟɪɚɬɭɪɵ ɦɢɧɟɪɚɥɨɨɛɪɚɡɭɸɳɟɣ ɫɪɟɞɵ.
Th, oC
450
Th, oC
A
B
450
Ʌɢɬɟɪɚɬɭɪɚ:
Ⱥɥɟɲɢɧ Ⱥ.ɉ., ȼɟɥɢɱɤɢɧ ȼ.ɂ., Ʉɪɵɥɨɜɚ Ɍ.Ʌ. Ƚɟɧɟɡɢɫ ɢ ɭɫɥɨɜɢɹ ɮɨɪɦɢɪɨɜɚɧɢɹ ɦɟɫɬɨɪɨɠɞɟɧɢɣ
ɭɧɢɤɚɥɶɧɨɝɨ ɦɨɥɢɛɞɟɧ-ɭɪɚɧɨɜɨɝɨ ɋɬɪɟɥɶɰɨɜɫɤɨɝɨ ɪɭɞɧɨɝɨ ɩɨɥɹ: ɧɨɜɵɟ ɦɢɧɟɪɚɥɨɝɨɝɟɨɯɢɦɢɱɟɫɤɢɟ ɢ ɮɢɡɢɤɨ-ɯɢɦɢɱɟɫɤɢɟ ɞɚɧɧɵɟ // Ƚɟɨɥ. ɪɭɞ. ɦɟɫɬ. 2007. Ɍ.49. ʋ5. ɋ.446-470.
Brown P.E. FLINCOR: // Amer. Mineralogist. 1989. V. 74. P. 101-127.
ɇɚɭɦɨɜ Ƚ.Ȼ. Ɉɫɧɨɜɵ ɮɢɡɢɤɨ-ɯɢɦɢɱɟɫɤɨɣ ɦɨɞɟɥɢ ɭɪɚɧɨɜɨɝɨ ɪɭɞɨɨɛɪɚɡɨɜɚɧɢɹ. // Ɇ.: Ⱥɬɨɦɢɡɞɚɬ,
1978.
67