!"#$%& !'*'#+,-./0.-1#2'3'#+,-45,1#6'+'#7849:4;##

!"#$%&
!"#$## #!"#$#%&'()*!+&",)-).##/!0)$ XXVI/!1231/!44 (133)
!"#$%&'()
!'*'#+,-./0.-1#2'3'#+,-45,1#6'+'#7849:4;##
<=884>8;4>#?4@4;=-A.?5=/=B4:.8;4>#C54-.D84A.A#4@'#!'E'#F.5G./..-,1#F=8;-,1#<=884H
!"#$%&'()* #'+ ,"+ -.",#/'+ ."!&'0"+ 1"!+ 2-%03,%'+
%0%4,%–56%4)#&,7(+%0#-%$'.
6#D,I=A.#489=/0J=-,5K#D,J/4:5K.#@.A=GK##488/.G=-,54H#9D=L.88=-#1#9D=A.;,MN4?#
5,# BD,54L.# D,JG./,# O,J'# EJC:.5=# -/4H54.# 9=-.D?5=8A5K?# H-/.54># -# 9=/[email protected]?#
;=@9=J4L4=55K?#@,A.D4,/,?#5,#8-=>8A-,#=A-.DPG.55K?#=ID,JL=-'#Q=;,J,5=1#:A=#--.G.54.#
@=G4O4;,A=D,#C/C:R,.A#@.PO,J5=.##-J,4@=G.>8A-4.#-#;=@9=J4A.'
Various methods for researching interfacial effects were used. Influence of polymer
composite interfacial interaction on cured specimens were studied. It was shown that addition of
modifiers improve composite molecular interaction.
6# 5,8A=HN..# -D.@H# 5,I/MG,.A8H# 8AD.@4A./05K># D=8A# 9D=4J-=G8A-,#
9=/[email protected]?# ;=@9=J4A=-1# 8=JG,54.# ;=A=DK?# 5.9=8D.G8A-.55=# 8-HJ,5=# 8#
489=/0J=-,54.@#B.A.D=B.55K?#9=/[email protected]?#848A.@'
Q=-.D?5=8A5K.# H-/.54H# -# ,D@4D=-,55K?# 9=/[email protected]?# @,A.D4,/,?#
4BD,MA# 8CN.8A-.55CM# D=/0# -=# -8.@# ;=@9/.;8.# 4?# 8-=>8A-# 41# 9D.PG.# -8.B=1# -#
8ADC;ACD5=-@.?,54:.8;4?# 8-=>8A-,?1# ,# 488/.G=-,54.# =8=I.55=8A.># 9=-.G.54H#
@,;D=@=/.;C/# 5,# BD,54L.# D,JG./,# O,J# H-/H.A8H# =G5=># 4J# -,P5.>R4?# J,G,:# -#
SA=>#=I/,8A4TUV'#75,#-;/M:,.A#A,;4.#-,P5K.#-=9D=8K1#;,;#,GB.J4M#9=/[email protected]=-#
;#A-.DGK@#9=-.D?5=8AH@1#8ADC;ACD5=-@.?,54:.8;4.#8-=>8A-,#BD,54:5K?#8/=.-#
9=/[email protected]=-1# 5,?=GHN4?8H# -# ;=5A,;A.# 8# A-.DGK@4# A./,@4# 4# @5=B=.# GDCB=.'# *=#
=85=-5=.# @.8A=# J,54@,.A# ,G8=DIL4H# 9=/[email protected]=-# 5,# 9=-.D?5=8A4# A-.DGK?#
-.N.8A-1#;=A=D,H#=9D.G./H.A#=8=I.55=8A4#8ADC;ACDK#BD,54:5=B=#8/=H1#?,D,;A.D#
C9,;=-;4# @,;D=@=/.;C/# -# BD,54:5K?# 8/=H?1# ,# =A8MG, – @=/.;C/HD5CM#
9=G-4P5=8A0#L.9.>#4#4?#D./,;8,L4=55K.#4#8-=>8A-,TWV'
*,4I=/..# 9.D89.;A4-5K@4# 8-HJCMN4@4# G/H# -K8=;=9D=:5K?#
,D@4D=-,55K?# ;=@9=J4L4=55K?# @,A.D4,/=-# H-/HMA8H# S9=;84G5K.#
=/[email protected]# TXV'# "# 4?# G=8A=458A-,@# 8/.GC.A# =A5.8A4# 54J;CM# C8,G;C# 9D4#
=A-.DPG.5441# ?=D=R4.# 9D=:5=8A5K.# ?,D,;A.D48A4;4# 4# -K8=;CM# ,GB.J4M# ;#
I=/0R458A-C# 5,9=/54A./.>'# Y9=;845=-=/,:5K.# =/[email protected]# H-/HMN4.8H#
D,J5=-4G5=8A0M# S9=;84G5K?# 8@=/1# I=/..# D.,;L4=55=89=8=I5K# 4# [email protected]#
9=-KR.55CM# A.D@=8A=>;=8A0# -# =A-.DPG.55=@# 8=8A=H544# 9=# 8D,-5.54M# 8#
AD,G4L4=55K@4#G4,5=-K@4#=/[email protected],@4'
[email protected].#8#A.@1#-8/.G8A-4.#-K8=;=>#-HJ;=8A4#S9=;845=-=/,:5K?#8@=/1#
[email protected]# A.?5=/=B4:.8;4.# ADCG5=8A4# 9D4# 9D=94A;.# ,D@4DCMN4?#
5,9=/54A./.># 9=/[email protected]@4# @,AD4L,@4# 5,# 4?# =85=-.'# 6# 8-HJ4# 8# SA4@#
C/C:R.54.# -J,4@=G.>8A-4H# @.PGC# 9=/[email protected]=># @,AD4L.># 4# ,D@4DCMN4@#
5,9=/54A./.@#H-/H.A8H#,;AC,/05=>#J,G,:.>'
+# L./0M# 9=-KR.54H# @.PO,J5=B=# -J,4@=G.>8A-4H# -# D,I=A.#
9D.G/=P.5=# 489=/0J=-,A0# ,;A4-5K.# D,JI,-4A./4# D,J/4:5=B=# 8AD=.54H# 4#
OC5;L4=5,/05=8A4'# E?# G=8A=458A-=# 8=8A=4A# -# A=@1# :A=# =54# 5.#
C/.AC:4-,MA8H'# Q=@4@=# SA=B=# =54# ,;A4-5=# C:,8A-CMA# -# 9D=L.88.#
84
!"#$%&
!"#$## #!"#$#%&'()*!+&",)-).##/!0)$ XXVI/!1231/!44 (133)
=A-.DPG.54H1# A';'# 8=G.DP,A# -# 8-=.@# 8=8A,-.# S9=;84G5K.# BDC99K1# ;=A=DK.#
89=8=I5K# -8AD,4-,A08H# -# 8ADC;ACDC# 9=/[email protected]=># @,AD4LK'# E89=/0J=-,54.#
,;A4-5K?# D,JI,-4A./.># A,;P.# 9=J-=/H.A# C/C:R4A0# 9D=:5=8A5K.# 4#
A.?5=/=B4:.8;4.#?,D,;A.D48A4;4#TZV'
6#G,55=>#D,I=A.#488/.G=-,5=#-/4H54.#G=I,-=;#D,J/4:5=>#9D4D=GK#5,#
9D=L.88K1# 9D=A.;,MN4.# 5,# 9=-.D?5=8A4# CB=/05=B=# -=/=;5,# 9D4# .B=#
-J,4@=G.>8A-44# 8=# 8-HJCMN4@'# 6# ;,:.8A-.# 8-HJCMN.B=# 489=/0J=-,/4#
S9=;845=-=/,:5K># =/[email protected]# [Y*7\1# =A-.DPG,.@K># ,/4O,A4:.8;4@#
,5B4GD4G=@'# 6# ;,:.8A-.# ,;A4-5K?# @=G4O4;,A=D=-# IK/4# 489=/0J=-,5K#
B/4L4G4/=-K.# SO4DK# []Y–U1# ]Y–W\1# SO4DCD.A,5=-K># ;,C:C;# [Y "\'#
Q=8;=/0;C# =A-.DPG.54.# S9=;84G5K?# 8@=/# ,5B4GD4G,@4# 9D=A.;,.A# ;D,>5.#
@.G/.55=1# -# 848A.@K# --=G4/4# AD.A4:5K># ,@45# -# ;,:.8A-.# ;,A,/4J,A=D,'#
7A-.DPG.54.# =ID,JL=-# CB/.9/,8A4;=-# 9D=-=G4/4# 9=# 8AC9.5:,A=@C# D.P4@C^#
U#:#9D4#UW(_+1#W#:#– U$(#_+1#U#:#– U&(_+'
E88/.G=-,54.#,G8=DIL44#8-HJCMN.B=#CB=/05K@#-=/=;5=@#9D=-=G4/4#
8/.GCMN4@#=ID,J=@^#=AD.J=;#CB=/05=>#/.5AK#[email protected],/4#-#U(`-5K>#D,8A-=D#
8-HJCMN.B=# -# ,L.A=5.1# ,# J,A.@# :.D.J# =9D.G./.55K.# [email protected];4# [email protected]#
=9D.G./H/4#=9A4:.8;CM#9/=A5=8A0#D,8A-=D,#[D48'U\'
16
2
2G8=DIL4H1#@BaB
14
3
12
10
8
1
6
4
4
2
0
0
5
10
15
20
25
6D.@H1#:
.89:+;:+ <8=>8?+@AB8C8DEFAGAH+>E+H?<8I8>J+EB9AGKL88+9H=MJNO?PA+JPA<Q>R@+
HA<AD>A@S+;+- 5,%T+U+- 5,%V524T+W+- 5,%V-5–1, 4 - 5,%V-5–2
QD.G-,D4A./05=# G/H# ;,PG=B=# 8-HJCMN.B=# IK/4# 9=8AD=.5K#
;,/4ID=-=:5K.#[email protected]#9=#;=A=DK@#=9D.G./H/4#;=5L.5AD,L4M#D,8A-=D,#9=#
=9A4:.8;=># 9/=A5=8A4'# Q=8AD=.5K# BD,O4;4# [email protected]# ;=5L.5AD,L44#
D,8A-=D=-#@=G4O4L4D=-,55K?#8-HJCMN4?#-=#[email protected]#9D4#-J,4@=G.>8A-44#8#
CB=/05=>#/.5A=>'
EJ# 9=/C:.55K?# G,55K?# -4G5=1# :A=# /C:R.># ,G8=DIL4.># ;#
5,9=/54A./M# =I/,G,.A# 8=8A,-1# @=G4O4L4D=-,55K># SO4DCD.A,5=-K@#
;,C:C;=@# [Y "\'# +-HJCMN..1# 5.# 8=G.DP,N..# @=G4O4;,A=D=-1# -# ?=G.#
G,55=B=# S;[email protected],# 9=;,J,/=# 8CN.8A-.55=# I=/..# 54J;=.# J5,:.54.#
85
!"#$%&
!"#$## #!"#$#%&'()*!+&",)-).##/!0)$ XXVI/!1231/!44 (133)
,G8=DIL44'# !,55=.# 9=-.G.54.1# -.D=HA5=1# @=P.A# IKA0# 8-HJ,5=# 8=#
89.L4O4:.8;4@4#-J,4@=G.>8A-4H@4#54J;=@=/.;C/HD5K?#;=@9=5.5A=-'
6# ?=G.# D,I=AK# A,;P.# IK/4# =9D.G./.5K# A,;4.# 9=-.D?5=8A5K.#
?,D,;A.D48A4;4# 488/.GC.@K?# 8=8A,-=-# ;,;# ;D,.-=># CB=/# 8@,:4-,54H#
9=G/=P;4#4J# CB=/05=B=#-=/=;5,1#9=-.D?5=8A5=.#5,AHP.54.1#D,I=A,#,GB.J441#
D,I=A,#8@,:4-,54H'
"D,.-=># CB=/# 8@,:4-,54H# =9D.G./H/4# @.A=G=@# /.P,:.># ;,9/4'#
Q=-.D?5=8A5=.# 5,AHP.54.# =9D.G./H/4# @.A=G=@# =ADK-,# 9/,8A45;4#
[@=G4O4L4D=-,55K># @.A=G# 9/,8A45;4# 64/0B./0@4\# 9D4# ;=@5,A5=>#
[email protected],ACD.#T)V'#b-/.54H#,GB.J44#4#8@,:4-,54H#A.85=#8-HJ,5K#@.PGC#8=I=>'#
c, -./4:45C# D,I=AK# ,GB.J44# 9D454@,MA# D,I=AC1# ;=A=DCM# 5.=I?=G4@=#
J,AD,A4A0# 5,# D,JDK-# 8=.G45.54H1# 9D4?=GHNCM8H# 5,# .G454LC# 9/=N,G4#
9=-.D?5=8A4'
*EK<:+;:+ <8=>8?+@AB8C8DEFAGAH+>E+XAH?GY>A9F>R?+9HAZ9FHE+9H=MJNO8Y
+=8A,-
cos
"D,.-=>#CB=/#
8@,:4-,54H# , !
Y*7
Y*7# e#
Y "
Y*7# e#
]Y–1
Y*7# e#
]Y–2
0,858
34,3
Q=-.D?5=8A5=.#
5,AHP.54.#d1#
@*a@
44,81
<,I=A,#
8@,:4-,54H#
W8@1#@*a@
38,45
<,I=A,#
,GB.J44#
Wa1#@*a@
83,26
0,828
37,9
48,64
40,30
88,94
0,904
28,1
43,95
39,71
83,66
0,899
28,9
45,46
40,86
86,32
",;# -4G5=# 4J# 9D4-.G.55K?# G,55K?# [A,I/'U\1# --.G.54.# B/4L4G4/=-K?#
SO4D=-# []Y–U# 4# ]Y–W\# -# 8-HJCMN..# C/C:R,.A# 8@,:4-,54.# 9=G/=P;41#
[email protected],H#;D,.-=>#CB=/#8@,:4-,54H1#-#A=#-D.@H#;,;#SO4DCD.A,5=-K>#;,C:C;#
[Y "\1# 5,9D=A4-1# C-./4:4-,.A# .B='# YA=# @=P5=# =IfH854A0# A.@1# :A=# Y "#
8=G.DP4A# 5,# ;=5L,?# S9=;84G5K.# BDC99K1# :A=# C-./4:4-,.A# 9=-.D?5=8A5=.#
5,AHP.54.# 848A.@K1# 9=-KR,.A# -HJ;=8A0'# <,I=A,# 8@,:4-,54H# 8-HJCMN4?# 8#
489=/0J=-,54.@#@=G4O4;,A=D=-#D,J/4:5=>#9D4D=GK#9D,;A4:.8;4#=G45,;=-=#
C-./4:4-,.A8H# 9=# 8D,-5.54M# 8# 5.@=G4O4L4D=-,55K@# 8=8A,-=@'# 7A@.:.5=#
J5,:4A./05=.# C-./4:.54.# D,I=AK# ,GB.J44# 9D4# 489=/0J=-,544# Y "'# YA=#
8-4G.A./08A-C.A# =# ?=D=R.># [email protected]@=8A4# ;=@9=5.5A=-1# 84/05=@#
@.PO,J5=@#-J,4@=G.>8A-44#4#9D=:5=>#,GB.J4=55=>#8-HJ4'
EJ-.8A5=1# :A=# 9D=:5=8A0# ,GB.J4=55K?# 8=.G45.54># J,-484A# =A#
9=/5=AK# ;=5A,;A,# 8=9D4;,8,MN4?8H# O,J'# Q=SA=@C# 9D4# G,/05.>R4?#
488/.G=-,54H?# =9D.G./H/4# ,GB.J4=55CM# 9D=:5=8A0# =A-.DPG.55K?#
8-HJCMN4?#5,#@.A,//4:.8;4?#9/,8A45,?'
QD=:5=8A0# 9D4# 8G-4B.# []7+g# UZ%$(-$h\# =9D.G./H/4# 5,#
@.A,//4:.8;4?#9/,8A45;,?1#8;/..55K?#-5,?/.8A#8-HJCMN4@1#=A-.DPG.55K@#
9=# C;,J,55=@C# D.P4@C'# E89KA,54H# 9D=-=G4/480# 9D4# 8;=D=8A4# W(# @@a@45'#
!,55K.# 9D.G8A,-/.5K# -# A,I/4L.# W'# <=8A# ,GB.J4=55=># 9D=:5=8A4#
@=G4O4L4D=-,55=B=# 8-HJCMN.B=# @=P5=# # =IfH854A0# C/C:R.55=>#
8@,:4-,MN.># 89=8=I5=8A0M# @,A.D4,/,# 4# -=J@=P5K@# G=9=/54A./05K@#
86
!"#$%&
!"#$## #!"#$#%&'()*!+&",)-).##/!0)$ XXVI/!1231/!44 (133)
-J,4@=G.>8A-4.@# J,# 8:.A# C-./4:.54H# :48/,# OC5;L4=5,/05K?# BDC991#
[email protected]?8H#C#,;A4-5K?#D,JI,-4A./.>'
*EK<:+U:+ <8=>8?+HH?B?>8=+@AB8C8DEFAGAH+>E+EBP?M8A>>JN+XGAI>A9FQ+9H=MJNO?PA
+=8A,-
2GB.J4=55,H#9D=:5=8A01#FQ,
8,79
10,6
9,45
9,25
Y*7
Y*7#e#Y "
Y*7#e#]Y–1
Y*7 e#]Y–2
*,# =85=-.# 9=/C:.55K?# D.JC/0A,A=-# 9=/C:.5K# =9KA5K.# =ID,JLK#
CB/.9/,8A4;=-# 8# /C:R4@4# 4J# 4JC:.55K?# @=G4O4L4D=-,55K?# 8-HJCMN4?'#
7A-.DPG.54.# 9D=?=G4/=# 9=# =948,55=@C# D.P4@C'# iK/4# =9D.G./.5K#
9D=:5=8A5K.# ?,D,;A.D48A4;4# 9=/C:.55K?# =ID,JL=-'# QD=:5=8A0# 9D4# 4JB4I.#
=9D.G./H/4#5,#489KA,A./05=>#@,R45.#GOTECHAL-7000S 9=#]7+g#W)'$(Z&W'# 79D.G./.54.# 9D=:5=8A4# =ID,JL=-# CB/.9/,8A4;=-# 9D4# D,8AHP.544# 9D4#
;=@5,A5=># [email protected],ACD.# =8CN.8A-/H/480# 9=# ]7+g# W)'$(U-&(# 5,#
489KA,A./05=># @,R45.# GOTECHAL-7000S'# E89KA,54H# 9D=-=G4/480# 9D4#
8;=D=8A4#W(#@@a@45'#!,55K.#489KA,54>#9D4-.G.5K#-#A,I/4L.#X'
*EK<:+W:+6GAI>A9F>R?+9HAZ9FHE+@AB8C8L8GAHE>>RY+[XAD98>AHA<EI>RY+9H=MJNO8Y
+=8A,Y*7
Y*7eY "
d4JB#1FQ,
1480
1750
dD#1FQ,
1550,1
1995,4
",;# -4G5=# 4J# G,55K?# A,I/'# X1# # 9D=:5=8A0# @=G4O4L4D=-,55K?#
CB/.9/,8A4;=-# 9D4# D,8AHP.544# 4# 9D4# 4JB4I.# 8CN.8A-.55=# -KR.# 9=#
8D,-5.54M#8#5.@=G4O4L4D=-,55K@4'#
g,;4@# =ID,J=@1# 9=;,J,5=1# :A=# 9D=L.88K1# 9D=A.;,MN4.# 5,# BD,54L.#
D,JG./,# O,J# -# 9=/[email protected]=@# ;=@9=J4A.1# =;,JK-,MA# -/4H54.# 5,# .B=#
?,D,;A.D48A4;4'# <,JD,I=A,5K# @=G4O4L4D=-,55K.# 8-HJCMN4.1# 488/.G=-,5K#
4?# 9=-.D?5=8A5K.# 8-=>8A-,1# 9D=-.G.5,# ;=DD./HL4H# @[email protected],J5K@#
-J,4@=G.>8A-4H@#4#9D=:5=8A5K@4#8-=>8A-,@4#;=@9=J4A=-'
i4I/4=BD,O4:.8;4.#88K/;4#
U'# Q.D.9./;45# "'j'# 2D@4DCMN4.# -=/=;5,# 4# -=/=;548AK.# 9=/[email protected].#
;=@9=J4AK#– +,5;A-Q.A.DICDB^#*7g1#W((h#'#X&(#8'
W'# k49,A=-# 3'+'1# +.DB..-,# k'F'# 2G8=DIL4H# 9=/[email protected]=- – "4.-^# *,C;=-,#
GC@;,1#Uh%W'– Uh$#8'
X'# FSAA0MJ# l'1# <=//45B8# <'# "=@9=J4A5K.# @,A.D4,/K'# F.?,54;,# 4#
A.?5=/=B4Ha#Q.D'#8#,5B/'#– F'^#g.?5=8O.D,1#W((Z'Z(&#8'
Z'#k49,A=-#2'+'#F,;D=@=/.;C/K#5,#BD,54L.#D,JG./,#O,J##– "4.-^#*,C;=-,#
GC@;,1#Uh%U'W$Z#8'
)'#Q,A.5A#RU 2 312 XWZ#+W1#G01N 13/02
87