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t has been studied by NMR 13C, FTIR, UV and GPC the chemical structure and molecular mass distribution of carbossimetilcellulose, obtained by homogeneous oxidation. It is found that oxidized units of dialdehydcarbossimetilcellulose exists in the form of semiacetal intramolecular bonded cycles. This structure has been registered both in solid state and in D2O solutions. Controlled periodate oxidation resulted in subsequent reduction of molecular weight and it is not resulted in cross-linking of the polymer. 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