169 Для кристаллов типа NaCl замещаемые атомы составляют

реклама
169
NaCl
(қ)
Nfreq/Natoms
–
,
–
ғ
,
,
,
θғ
ғ
ғ
(
ғ
,
ғ
1.
,
)
ln
ғ
ғ,
ғ ғ,
–
ғ ғ
ғ
ғ//
ғ ғ ғ
«
–
». - ғҮ4. -2007. – ғ
157-160.
2.
Urey H.C., Bradley C.A. The vibrations of pentatomic tetrahedral molecules. – Phys. Rev.,
1931, v. 38, p. 1969 – 1978.
3.
ғ ғ
ғ–
ғ – 2009. –
ғ - ғ қγγғ
4.
Bigeleisen J.//Proc.Nat.Acad.Sci.USA.Phys.Sci. -1981.- VғҮү, Ұғ - P.5271.
5.
ғ ғ,
ғ ғ
–
ғғ–
1999. - ғҮγ, ηғ - ғүҮη – 879.
6.
Barron T.H.K., Berg W.T., Morrison J.A.// Proc. Royal. Soc. - 1957. - V.250, 1260. P.70.
7.
Myrzaliyeva S.K., Dauletbai A.D. To the problem of search of perspective chemical
interchange systems for division of isotopes of biogenic elements // 14th Conference on Environment and
Mineral Processing, OSTRAVA. - Part 1. – 2010. – P. 251-255.
ғ ғ
,
ғ ғ
, ғ ғ
, ғ ғ
, .
-mail: [email protected]
,
, ғ ғ
-
ДҚ, қЖғ
,
ДҚЖ,
ғ
pH,
,
ғ
Дγ–5].
ДθЖ,
,
,
,
,
,
,
ғ
Mn(OH)m
ғ
,
ғ
ғ
ғ
,
170
ғ
100C.
Қ0η–ҚҚ0º ғ
NaCl, %
3
3
5
15
15
20
25
25
қ0–Ү0
ДҮЖғ
)
(
ғ
SDT
γ%
NaCl
ғ Қ),
γ%-
,
ДүЖғ
SnO2
SnO
Sn2O3
ғ
2
),
SnO
,
SnO2 (
қη%
ғ
,
Қ0 /
,
Sn3O4
,
ғ
SnO2
қ)ғ
,
SnO
Qθ00
-
, U=қ0
SnO
)
(I=қ0
(қ)
SnO2
(
SnO
2 /
)
-
, /
2,0
3,0
3,0
1,0
2,0
3,0
2,0
2,5
SnO
SnO2 (
,
ғ,
ғ
SnO2
(
Cu
-γ
,
ғ
SnO2
1
2
3
4
5
6
7
8
,
ғ
1
2
20
30
40
50
60
70
2,
Қ қ
ғ Қғ
,
,
SnO
,
ғ
SnO2
Sn2O3
NaCl c
Sn3O4.
,
γ%
ғ
171
SnO
SnO
SnO2
SnO2
SnO2
SnO
SnO2
SnO
8
7
20
30
40
50
60
2
Ү ү
ғ қғ
ғ
(
ғ 3, 4)
,
-
Қ-4 (
ғ 3, 4)
ғ
-
,
Қ,
қ00–250
70
ηη0–750 ғ
(IV)ғ
-
,
ғ
Қ–4
,
SnO2
,
SnO,
-
Қү0–200, 300–310, 380–400
ғ
(Ққ–14%
(
ғ)
(II),
(IV)ғ
Sn(OH)2.
ғ 3, 4)
4θ0–470 ,
,
SnO2 nH2O,
m, %
101
қ–4
n=1,6–1,8.
Q, /
0,5
99
0,3
2
1
0,1
97
1
95
2
93
0
300
600
,
ғ γғ
(
ғ)ғ
,
(
ғ 4),
SnO2ғ
-0,1
-0,3
900
Қ қ
(Ққ0–480 )
(IV)
172
4ү0–900 ғ
SnO2ғ
SnO2
ғ
4η0
m, %
101
,
,
,
Q, /
0,30
3
99
0,15
4
97
0,00
3
-0,15
95
4
93
0
,
γ
Ү ү,
ғ η)ғ
(
,
ғ
,
-0,30
900
600
[9].
ғ 4ғ
-
300
ғ
Үқ0 ғ
ғ
m, %
101
қη%
NaCl
γҮ0–430
4,0
,
θ,η%ғ
,
4
ғ,
SnO
,
-
Q, /
1
1,0
100
8
0.8
0,8
99
7
0.6
0,6
0.4
0,4
98
0.2
0,2
97
7
96
0
0,0
8
-0.2
-0,2
95
-0.4
-0,40
900
94
0
300
600
,
ғ ηғ
-
,
Ү
(
),
ДҚ0, ҚҚЖғ
ғ
η
,
SnO,
ү
,
θ –
,
SnO2,
173
( зқ
γү0–720
η θ
620–640 ғ
,
)
қη%
NaCl
(
ғ
SnO
),
,
SnO2ғ
,
NaCl
Sn(OH)2ғ
,
,
,
,
–
4қ0 ғ
Қη%
ғ
ғ
,
,
ηҚ0–ηқ0
γү0 ,
SnO,
,
6
,%
5
4
3
1
2
3
4
2
1
0
0
10
20
30
ғ 6.
40
50
60
,
Қ-4
.
6
,%
5
4
3
5
6
7
8
2
1
0
0
ғ Үғ
10
20
30
40
60
,
η-ү,
Ұ00 ,
ғ
50
-
-
,
ғ
,
174
ғθ
Үғ
ғθ
Ү
,
,
ғ
θ,Қ%,
,
қη%
NaCl
,
ғ
,
,
NaCl
ғ
,
,
ұ
,
γ,қ–
γ%
ғ,
ғ, – 1,9–4,3%.
Cl–
,
ДθЖ,
ғ
,
ғ
,
ғ
қη%
γ%
SnO2ғ
ғ
ғ,
SnO.
1. Pourbaix M. Atlas of Electrochemical Equilibria in Aqueous Solutions. – L.: Pergamon Press, 1966.
Pt. 2. – 386 p.
2.
ғ ғ
ғ – ғұ
, ҚҰҮ4ғ – 71 ғ
3.
ғ ғ,
ғ ғ,
ғ ғ,
ғ ғ
4.
5.
ғ
//
ғ – 1985. – ғ 21. – 10. – ғ 1287–1292.
ғ – ғұ
, ҚҰθҮғ – 232 ғ
ғ ғ
ғ–
ұ
, ҚҰүηғ – 280 ғ
6.
ғ
//
ғ –
2000. – ғ 36. – 10. – ғ – 1191–1196.
7. ASTM Diffraction date cards and alphabetical and grouped numerical index of X–ray diffraction
date. Philadelphia, ASTM, 1967.
8.
ғ ғ,
ғ ғ
,
//
ғ – 2004. – ғ 307. –
4. – ғ 101–104.
9.
ғ ғ,
ғ ғ,
ғ ғ,
ғ ғ,
ғ ғ,
ғ ғ
//
ғ – 1994. – ғ 30. – 1. – ғ 83–86.
10.
ғ ғ,
ғ ғ,
ғ ғ,
ғ ғ
//
ғ –
2002. – ғ 38. – 9. – ғ 1087–1090.
11.
ғ ғ,
ғ ғ
,
//
ғ – 2003. – ғ 306. – 3. – ғ 89–94.
Скачать