1. . , @ : ; ; ; 1. 2. 3. 4. . , . . . . . 5. - N- ( , , ). 6. . : 1. 1. 1. 1 2 3 4 5 6 7 8 9 10 ( ) 2. , , , , , , , . 3. , , . 4. 5. , 164 . , , , , , . 6. . , , . 7. : 8. ) ; ) ; ) ; . , : 1 ) , , @ 1. . . , . (II) ( ) . - . : 5 3 10% NaOH 1 10% CuSO4, . : ______________________________________________________________ _______________________________________________________________________________ _______________________________________________________________________________ : : ___________________________________________________________________ _______________________________________________________________________________ 2. . . , : , , . , . . : 5 2-3 HNO3, . : ______________________________________________________________ _______________________________________________________________________________ _______________________________________________________________________________ 1,5 10% NaOH . : ______________________________________________________________ _______________________________________________________________________________ _______________________________________________________________________________ : : ___________________________________________________________________ _______________________________________________________________________________ 2 3. . . @ , . : 5 5 0,6 5% . . . : ______________________________________________________________ _______________________________________________________________________________ _______________________________________________________________________________ : ___________________________________________________________________ _______________________________________________________________________________ _______________________________________________________________________________ 1. : , , , , , , – : , , , , ; – . , , 2. 26000 , , , . . , ; – , . , ) , . , : , , . Halobacterium halobium , 4,5 ( . 1). ( %) , , , , , . , 110 . .1 2 : , , ; ; . 1. ( , ). 3 2. . , 3. 4. ( , ). . , . @ . : 1. 2. 2. , 2. pH pI pH = 3,0 pH = 5,6 : pH = 8,0 – – – 3. , , , , pH = 6,2. ( , , pH 6,2 ) , . 4. : 1 – 12 , 2 – 19 Rf ; , 0,48; – 0,32; – 40 3 – 25 ; ; . – : – 0,38. 1. ( ) . , , . . , , . . , , . , , , , , . . 4 . , . . @ : . . 5 1–2 1% CuSO4. : ______________________________________________________________ _______________________________________________________________________________ _______________________________________________________________________________ 1 , 2–5 10% CuSO4. : ______________________________________________________________ _______________________________________________________________________________ _______________________________________________________________________________ . ( ). 5 ( 45°, , ) . , . : ______________________________________________________________ _______________________________________________________________________________ _______________________________________________________________________________ . . 5 96% . : ______________________________________________________________ _______________________________________________________________________________ _______________________________________________________________________________ . : ___________________________________________________________________ _______________________________________________________________________________ 2. . . – , , = 7, . , , 0, ). . . : . 5 96% 1% 4,75 1,0 1,5 0,5 3,4 1,0 1,5 0,5 @ 5,7 1,0 1,5 0,5 : ___________________________________________________________________ _______________________________________________________________________________ 1. pH 6,5 . , , , , : ) ) ; . . 2. , 39%, 3( . 100%. 25000) – 63%, 15000) 2 ( 35000) 4 ( 20000) – 81% 1 ( 1. , 2 3. 3. ( . 3). . 3 pI 151000 150000 37100 - 4,4 6,3 5,2 3 « , » : , ; . 1. 2. 3. 4. . , , , . . . . , , 5. . , . , 6. , 7. 8. , , -, - . ). ( . . . . . . , . 6 . : 1. , . , , @ 2. . 3. 4. . ( , , ) 5. 6. . , , , ; . 7. . , . 8. . . . 9. . . . 10. 4. 4. 1. E7 , , , . Fe2+ Fe3+. ) ) ? , , ? ) ? 2. « » . ) ) ) ? , 2 2, 3. – ? 2, ? 2,38,0 ) ) ) 0,5 , 2,3- . . ? 2,3- 2 ) , 3 4. 2,3? , , , . , , , ? 7